{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T16:53:40Z","timestamp":1785430420504,"version":"3.56.0"},"reference-count":16,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2023,10,19]],"date-time":"2023-10-19T00:00:00Z","timestamp":1697673600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,10,19]],"date-time":"2023-10-19T00:00:00Z","timestamp":1697673600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/100007875","name":"Tulane University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100007875","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2023,10,14]]},"published-print":{"date-parts":[[2023,10,28]]},"abstract":"<jats:p>\n                    The conformation of the title molecule, C\n                    <jats:sub>20<\/jats:sub>\n                    H\n                    <jats:sub>17<\/jats:sub>\n                    ClFN\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    , is partly determined by an intramolecular C\u2014H...O hydrogen bond, which leads to a dihedral angle of 14.7\u2005(4)\u00b0 between the fluorobenzene ring and the acetamide group. The 2-chlorobenzyl group is rotationally disordered over two orientations in a 0.656\u2005(2): 0.344\u2005(2) ratio. In the crystal, a layered structure is formed by N\u2014H...O, C\u2014H...O and C\u2014H...F hydrogen bonds plus slipped \u03c0\u2013\u03c0 stacking interactions.\n                  <\/jats:p>","DOI":"10.1107\/s241431462300901x","type":"journal-article","created":{"date-parts":[[2023,10,19]],"date-time":"2023-10-19T11:08:05Z","timestamp":1697713685000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["2-[4-(2-Chlorobenzyl)-3-methyl-6-oxo-1,6-dihydropyridazin-1-yl]-\n                    <i>N<\/i>\n                    -(4-fluorophenyl)acetamide"],"prefix":"10.1107","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8318-157X","authenticated-orcid":true,"given":"Hamza","family":"Assila","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00r8w8f84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3736-2545","authenticated-orcid":true,"given":"Issam","family":"Ameziane El Hassani","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00r8w8f84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4846-4547","authenticated-orcid":true,"given":"Abderrazzak","family":"El Moutaouakil Ala Allah","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00r8w8f84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abdulsalam","family":"Alsubari","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3488-1945","authenticated-orcid":true,"given":"Joel T","family":"Mague","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6885-5692","authenticated-orcid":true,"given":"Youssef","family":"Ramli","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00r8w8f84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"MHammed","family":"Ansar","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00r8w8f84","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,10,19]]},"reference":[{"key":"hb4454_bb1","first-page":"231","volume":"26","author":"Abiha","year":"2018","journal-title":"Rev. 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