{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T14:58:13Z","timestamp":1785423493758,"version":"3.56.0"},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2023,10,19]],"date-time":"2023-10-19T00:00:00Z","timestamp":1697673600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,10,19]],"date-time":"2023-10-19T00:00:00Z","timestamp":1697673600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2023,10,14]]},"published-print":{"date-parts":[[2023,10,28]]},"abstract":"<jats:p>\n                    The synthesis and crystal structure of a new triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetrafluoridoborate counter-anion and solvating dichloromethane, [Ir(C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    )(C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>13<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    )(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    P)]BF\n                    <jats:sub>4<\/jats:sub>\n                    \u00b71.5CH\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    , is reported. The Ir\n                    <jats:sup>I<\/jats:sup>\n                    center of the cationic complex has a distorted square-planar conformation, formed by a bidentate cycloocta-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a triphenylphosphane ligand. There are weak hydrogen-bonding interactions between C\u2014H groupings of the iridium complex and F atoms of the [BF\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    counter-ions. The atoms of the COD ligand are disordered over two sets of sites in a 0.65:0.35 ratio and two of the F atoms of the anion are disordered over adjacent sites in a 0.6:0.4 ratio. One of the dichloromethane solvent molecules is disordered about an inversion center with 0.5 occupancy.\n                  <\/jats:p>","DOI":"10.1107\/s2414314623009033","type":"journal-article","created":{"date-parts":[[2023,10,17]],"date-time":"2023-10-17T07:39:07Z","timestamp":1697528347000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["[(1,2,5,6-\u03b7)-Cycloocta-1,5-diene](1-ethyl-4-isopropyl-1,2,4-triazol-5-ylidene)(triphenylphosphane)iridium(I) tetrafluoridoborate dichloromethane sesquisolvate"],"prefix":"10.1107","volume":"8","author":[{"given":"Aaron","family":"Maynard","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02x2aj034","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4790-6980","authenticated-orcid":true,"given":"Michael","family":"Gau","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00b30xv10","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4817-3915","authenticated-orcid":true,"given":"Daniel R.","family":"Albert","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02x2aj034","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Edward","family":"Rajaseelan","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02x2aj034","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,10,19]]},"reference":[{"key":"hb4453_bb1","doi-asserted-by":"crossref","first-page":"3596","DOI":"10.1021\/om020338x","volume":"21","author":"Albrecht","year":"2002","journal-title":"Organometallics"},{"key":"hb4453_bb2","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1107\/S2053273314022207","volume":"71","author":"Bourhis","year":"2015","journal-title":"Acta Cryst. 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