{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,5,14]],"date-time":"2025-05-14T00:12:43Z","timestamp":1747181563275,"version":"3.40.5"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2024,4,26]],"date-time":"2024-04-26T00:00:00Z","timestamp":1714089600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,4,26]],"date-time":"2024-04-26T00:00:00Z","timestamp":1714089600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Government of Brunei Darussalam","award":["UBD\/RSCH\/1.4\/FICBF(b)\/2022\/043","UBD\/RSCH\/1.4\/FICBF(b)\/2020\/024"],"award-info":[{"award-number":["UBD\/RSCH\/1.4\/FICBF(b)\/2022\/043","UBD\/RSCH\/1.4\/FICBF(b)\/2020\/024"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2024,4,17]]},"published-print":{"date-parts":[[2024,4,28]]},"abstract":"<jats:p>In the title compound, [Ni(C<jats:sub>13<\/jats:sub>H<jats:sub>13<\/jats:sub>N<jats:sub>4<\/jats:sub>S)<jats:sub>2<\/jats:sub>]\u00b70.33CH<jats:sub>3<\/jats:sub>OH\u00b70.67H<jats:sub>2<\/jats:sub>O, the Ni<jats:sup>II<\/jats:sup> atom is coordinated by two tridentate quinoline-2-carboxaldehyde 4-ethylthiosemicarbazonate ligands in a distorted octahedral shape. At 100\u2005K, the crystal symmetry is monoclinic (space group <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>n<\/jats:italic>). A mixture of water and methanol crystallizes with the title complex, and one of the ethyl groups in the coordinating ligands is disordered over two positions, with an occupancy ratio of 58:42. There is intermolecular hydrogen bonding between the solvent molecules and the amine and thiolate groups in the ligands. No other significant interactions are present in the crystal packing.<\/jats:p>","DOI":"10.1107\/s2414314624003390","type":"journal-article","created":{"date-parts":[[2024,4,26]],"date-time":"2024-04-26T07:43:41Z","timestamp":1714117421000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["<i>mer<\/i>-Bis(quinoline-2-carboxaldehyde 4-ethylthiosemicarbazonato)nickel(II) methanol 0.33-solvate 0.67-hydrate"],"prefix":"10.1107","volume":"9","author":[{"given":"Raudhatul Nadhirah","family":"Awang Adam","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7088-8859","authenticated-orcid":true,"given":"Natasha Ann","family":"Keasberry","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7494-0968","authenticated-orcid":true,"given":"Malai Haniti","family":"Sheikh Abdul Hamid","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,4,26]]},"reference":[{"key":"bh4083_bb1","doi-asserted-by":"crossref","unstructured":"Arif, R., Akrema,, Pulaganti, M., Rubab, U., Ali, A., Khan, M. 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