{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T09:35:01Z","timestamp":1785404101459,"version":"3.56.0"},"reference-count":13,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2024,4,30]],"date-time":"2024-04-30T00:00:00Z","timestamp":1714435200000},"content-version":"vor","delay-in-days":2,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,4,30]],"date-time":"2024-04-30T00:00:00Z","timestamp":1714435200000},"content-version":"tdm","delay-in-days":2,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2024,4,19]]},"published-print":{"date-parts":[[2024,4,28]]},"abstract":"<jats:p>\n                    The title compound, C\n                    <jats:sub>22<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    , crystallizes in space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>c<\/jats:italic>\n                    with four molecules in the asymmetric unit. The heterocyclic molecule is quasi-planar with a dihedral angle between the phenyl rings on the periphery of the molecule of 1.73\u2005(19)\u00b0. Short H...S (2.92\u2005\u00c5) and C\u2014H...\u03c0 [2.836\u2005(3)\u2005\u00c5] contacts are observed in the crystal with shorted\n                    <jats:italic>\u03c0<\/jats:italic>\n                    \u2013\u03c0 stacking distances of 3.438\u2005(3)\u2005\u00c5 along the\n                    <jats:italic>b<\/jats:italic>\n                    axis. Surprisingly, and unlike a closely related material, this molecule readily forms large crystals by sublimation and by slow evaporation from dichloromethane. The maximum absorbance in the UV-Vis spectrum is at 533\u2005nm. Emission was measured upon excitation at 533\u2005nm with a fluorescence \u03bb\n                    <jats:sub>max<\/jats:sub>\n                    of 658\u2005nm and cutoff of 900\u2005nm.\n                  <\/jats:p>","DOI":"10.1107\/s2414314624003572","type":"journal-article","created":{"date-parts":[[2024,4,24]],"date-time":"2024-04-24T09:57:22Z","timestamp":1713952642000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Benzo[\n                    <i>a<\/i>\n                    ][1,4]benzothiazino[3,2-\n                    <i>c<\/i>\n                    ]phenothiazine"],"prefix":"10.1107","volume":"9","author":[{"given":"Mamoun M.","family":"Bader","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00cdrtq48","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9719-5478","authenticated-orcid":true,"given":"Phuong-Truc T.","family":"Pham","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04p491231","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Salma S.","family":"Abu Khodair","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maysoon I.","family":"Saleh","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05k89ew48","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,4,30]]},"reference":[{"key":"oi4001_bb1","doi-asserted-by":"crossref","first-page":"2155","DOI":"10.1021\/jo01299a024","volume":"45","author":"Agarwal","year":"1980","journal-title":"J. Org. Chem."},{"key":"oi4001_bb3","unstructured":"Bruker (2014). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"oi4001_bb4","doi-asserted-by":"crossref","unstructured":"Feister, C., Pham, P.-T. T. & Bradley, A. (2023). MRS Advances, pp. 889-893. https:\/\/doi.org\/10.1557\/s43580-023-00609-y","DOI":"10.1557\/s43580-023-00609-y"},{"key":"oi4001_bb5","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"oi4001_bb6","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"oi4001_bb7","doi-asserted-by":"crossref","first-page":"4386","DOI":"10.1021\/j100374a003","volume":"94","author":"McLean","year":"1990","journal-title":"J. Phys. Chem."},{"key":"oi4001_bb8","doi-asserted-by":"crossref","unstructured":"McLean, M. R., Bader, M., Dalton, L. R., Devine, L. R. S. & Steier, W. H. (1989). MRS Online Proceedings Library, 173, 563-566. https:\/\/doi.org\/10.1557\/PROC-173-563","DOI":"10.1557\/PROC-173-563"},{"key":"oi4001_bb9","doi-asserted-by":"crossref","first-page":"1187","DOI":"10.1016\/S0040-4020(01)85898-1","volume":"44","author":"Okafor","year":"1988","journal-title":"Tetrahedron"},{"key":"oi4001_bb11","doi-asserted-by":"crossref","first-page":"7968","DOI":"10.1021\/jp712044u","volume":"112","author":"Pham","year":"2008","journal-title":"J. Phys. Chem. C"},{"key":"oi4001_bb12","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"oi4001_bb13","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"oi4001_bb14","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"oi4001_bb15","doi-asserted-by":"crossref","first-page":"149","DOI":"10.1117\/12.962119","volume":"1147","author":"Spangler","year":"1989","journal-title":"Proc. SPIE"}],"container-title":["IUCrData"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2024\/04\/00\/oi4001\/oi4001.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2024\/04\/00\/oi4001\/oi4001.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,7,3]],"date-time":"2024-07-03T09:51:15Z","timestamp":1720000275000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2414314624003572"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,4,28]]},"references-count":13,"journal-issue":{"issue":"4","published-online":{"date-parts":[[2024,4]]}},"alternative-id":["S2414314624003572"],"URL":"https:\/\/doi.org\/10.1107\/s2414314624003572","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2414314624003572\/oi4001sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314624003572\/oi4001Isup5.hkl","asserted-by":"subject"}]},"ISSN":["2414-3146"],"issn-type":[{"value":"2414-3146","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,4,28]]},"assertion":[{"value":"IUCrData","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/x"},"group":{"name":"general","label":"General"}},{"value":"data reports","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/x\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?oi4001","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"3 April 2024","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"19 April 2024","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"30 April 2024","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This data article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?oi4001"}},{"value":"\u00a9 2024 Bader\n                      et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}],"article-number":"x240357"}}