{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,5,14]],"date-time":"2025-05-14T00:12:44Z","timestamp":1747181564826,"version":"3.40.5"},"reference-count":17,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2024,5,31]],"date-time":"2024-05-31T00:00:00Z","timestamp":1717113600000},"content-version":"vor","delay-in-days":3,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,5,31]],"date-time":"2024-05-31T00:00:00Z","timestamp":1717113600000},"content-version":"tdm","delay-in-days":3,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100018992","name":"Fonds der Chemischen Industrie","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100018992","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2024,5,22]]},"published-print":{"date-parts":[[2024,5,28]]},"abstract":"<jats:p>Transamination of Sn(NMe<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub> with H<jats:sub>2<\/jats:sub>NMes (Mes is 2,4,6-trimethylphenyl, C<jats:sub>9<\/jats:sub>H<jats:sub>11<\/jats:sub>) led to the formation of the title compound, [Sn(C<jats:sub>9<\/jats:sub>H<jats:sub>12<\/jats:sub>N)<jats:sub>4<\/jats:sub>] or Sn(NHMes)<jats:sub>4<\/jats:sub>, which crystallizes in the tetragonal space group <jats:italic>P<\/jats:italic>\\overline{4}2<jats:sub>1<\/jats:sub>\n                  <jats:italic>c<\/jats:italic>, with four formula units per unit cell. The molecular structure consists of a central tin(IV) atom, which is surrounded by four NHMes groups. Sn(NHMes)<jats:sub>4<\/jats:sub> possesses crystallographically imposed \\overline{4} symmetry. The SnN<jats:sub>4<\/jats:sub> coordination polyhedron is best described as a compressed bisphenoid.<\/jats:p>","DOI":"10.1107\/s2414314624004796","type":"journal-article","created":{"date-parts":[[2024,5,31]],"date-time":"2024-05-31T08:13:34Z","timestamp":1717143214000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Tetrakis(2,4,6-trimethylanilido)tin(IV)"],"prefix":"10.1107","volume":"9","author":[{"given":"Christian","family":"L\u00e4mmer","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6349-347X","authenticated-orcid":true,"given":"Kurt","family":"Merzweiler","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,5,31]]},"reference":[{"key":"wm4214_bb1","doi-asserted-by":"crossref","first-page":"1180","DOI":"10.1107\/S0108270190001548","volume":"46","author":"Andersch","year":"1990","journal-title":"Acta Cryst. C"},{"key":"wm4214_bb2","doi-asserted-by":"crossref","first-page":"1383","DOI":"10.1039\/a802590h","author":"Beswick","year":"1998","journal-title":"Chem. Commun."},{"key":"wm4214_bb3","unstructured":"Brandenburg, K. (2019). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"wm4214_bb4","unstructured":"Coppens, P. (1970). The Evaluation of Absorption and Extinction in Single-Crystal Structure Analysis. In Crystallographic Computing edited by F. R. Ahmed, pp. 255-270. Copenhagen: Munksgaard."},{"key":"wm4214_bb5","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"wm4214_bb6","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1524\/ncrs.2003.218.2.201","volume":"218","author":"Engering","year":"2003","journal-title":"Z. Kristallogr. New Cryst. Struct."},{"key":"wm4214_bb7","doi-asserted-by":"crossref","first-page":"99","DOI":"10.1002\/zaac.19926100116","volume":"610","author":"Jansen","year":"1992","journal-title":"Z. Anorg. Allge Chem."},{"key":"wm4214_bb8","doi-asserted-by":"crossref","first-page":"4338","DOI":"10.1002\/ejic.200300397","author":"Janssen","year":"2003","journal-title":"Eur. J. Inorg. Chem."},{"key":"wm4214_bb9","doi-asserted-by":"crossref","first-page":"1944","DOI":"10.1039\/jr9650001944","author":"Jones","year":"1965","journal-title":"J. Chem. Soc."},{"key":"wm4214_bb10","doi-asserted-by":"crossref","first-page":"735","DOI":"10.1002\/(SICI)1521-3749(199905)625:5<735::AID-ZAAC735>3.0.CO;2-P","volume":"625","author":"L\u00e4mmer","year":"1999","journal-title":"Z. Anorg. Allg. Chem."},{"key":"wm4214_bb11","doi-asserted-by":"crossref","first-page":"16156","DOI":"10.1039\/C5DT01980J","volume":"44","author":"Lichtscheidl","year":"2015","journal-title":"Dalton Trans."},{"key":"wm4214_bb12","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1107\/S2052519213010014","volume":"69","author":"Parsons","year":"2013","journal-title":"Acta Cryst. B"},{"key":"wm4214_bb13","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1016\/0022-328X(89)85022-3","volume":"373","author":"Puff","year":"1989","journal-title":"J. Organomet. Chem."},{"key":"wm4214_bb14","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"wm4214_bb15","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"wm4214_bb16","unstructured":"Stoe & Cie (2016). X-AREA and X-RED32. Stoe & Cie, Darmstadt, Germany."},{"key":"wm4214_bb17","doi-asserted-by":"crossref","first-page":"955","DOI":"10.1039\/B617136B","author":"Yang","year":"2007","journal-title":"Dalton Trans."}],"container-title":["IUCrData"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2024\/05\/00\/wm4214\/wm4214.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2024\/05\/00\/wm4214\/wm4214.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,6,28]],"date-time":"2024-06-28T09:41:37Z","timestamp":1719567697000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2414314624004796"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,5,28]]},"references-count":17,"journal-issue":{"issue":"5","published-online":{"date-parts":[[2024,5]]}},"alternative-id":["S2414314624004796"],"URL":"https:\/\/doi.org\/10.1107\/s2414314624004796","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2414314624004796\/wm4214sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314624004796\/wm4214Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2414-3146"],"issn-type":[{"type":"electronic","value":"2414-3146"}],"subject":[],"published":{"date-parts":[[2024,5,28]]},"assertion":[{"value":"IUCrData","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/x"},"group":{"name":"general","label":"General"}},{"value":"data reports","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/x\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?wm4214","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"7 May 2024","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"22 May 2024","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"31 May 2024","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This data article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm4214"}},{"value":"\u00a9 2024 L\u00e4mmer and Merzweiler","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}],"article-number":"x240479"}}