{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,9]],"date-time":"2026-11-09T11:22:57Z","timestamp":1794223377888,"version":"4.8.0"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2024,6,4]],"date-time":"2024-06-04T00:00:00Z","timestamp":1717459200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,6,4]],"date-time":"2024-06-04T00:00:00Z","timestamp":1717459200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"University of Chinese Academy of Sciences","id":[{"id":"https:\/\/ror.org\/05qbk4x57","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2024,5,27]]},"published-print":{"date-parts":[[2024,6,28]]},"abstract":"<jats:p>\n                    The title compound, [Fe(C\n                    <jats:sub>84<\/jats:sub>\n                    H\n                    <jats:sub>52<\/jats:sub>\n                    N\n                    <jats:sub>12<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )Cl], crystallizes in space group\n                    <jats:italic>C<\/jats:italic>\n                    2\n                    <jats:italic>\/c<\/jats:italic>\n                    . The central Fe\n                    <jats:sup>III<\/jats:sup>\n                    cation (site symmetry 2) is coordinated in a fivefold manner, with four pyrrole N atoms of the porphyrin core in the basal sites and one Cl atom (site symmetry 2) in the apical position, which completes a slightly distorted square-pyramidal environment. The porphyrin macrocycle shows a characteristic ruffled-shape distortion and the iron atom is displaced out of the porphyrin plane by 0.42\u2005\u00c5 with the average Fe\u2014N distance being 2.054\u2005(4)\u2005\u00c5; the Fe\u2014Cl bond length is 2.2042\u2005(7)\u2005\u00c5. Intermolecular C\u2014H...N and C\u2014H...O hydrogen bonds occur in the crystal structure.\n                  <\/jats:p>","DOI":"10.1107\/s2414314624004966","type":"journal-article","created":{"date-parts":[[2024,5,29]],"date-time":"2024-05-29T06:22:56Z","timestamp":1716963776000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Chlorido[5,10,15,20-tetrakis(quinoline-7-carboxamido)porphinato]iron(III)"],"prefix":"10.1107","volume":"9","author":[{"given":"Jun","family":"Yang","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05qbk4x57","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cuijuan","family":"Zhang","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05qbk4x57","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaxiang","family":"Chu","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05qbk4x57","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,6,4]]},"reference":[{"key":"hb4470_bb1","doi-asserted-by":"crossref","first-page":"10840","DOI":"10.1021\/acs.chemrev.8b00074","volume":"118","author":"Adam","year":"2018","journal-title":"Chem. 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