{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T17:56:37Z","timestamp":1785434197821,"version":"3.56.0"},"reference-count":13,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2024,6,4]],"date-time":"2024-06-04T00:00:00Z","timestamp":1717459200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,6,4]],"date-time":"2024-06-04T00:00:00Z","timestamp":1717459200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"the University of Chinese Academy of Sciences"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2024,5,27]]},"published-print":{"date-parts":[[2024,6,28]]},"abstract":"<jats:p>\n                    In the title compound, [Mn(C\n                    <jats:sub>68<\/jats:sub>\n                    H\n                    <jats:sub>44<\/jats:sub>\n                    N\n                    <jats:sub>12<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )(C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )]\u00b72C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    Cl, the central Mn\n                    <jats:sup>II<\/jats:sup>\n                    ion is coordinated by four pyrrole N atoms of the porphyrin core in the basal sites and one N atom of the 2,5-dimethylimidazole ligand in the apical site. Two chlorobenzene solvent molecules are also present in the asymmetric unit. Due to the apical imidazole ligand, the Mn atom is displaced out of the 24-atom porphyrin mean plane by 0.66\u2005\u00c5. The average Mn\u2014N\n                    <jats:sub>p<\/jats:sub>\n                    (p = porphyrin) bond length is 2.143\u2005(8)\u2005\u00c5, and the axial Mn\u2014N\n                    <jats:sub>Im<\/jats:sub>\n                    (Im = 2,5-dimethylimidazole) bond length is 2.171\u2005(8)\u2005\u00c5. The structure displays intermolecular and intramolecular N\u2014H...O, N\u2014H...N, C\u2014H...O and C\u2014H...N hydrogen bonding. The crystal studied was refined as a two-component inversion twin.\n                  <\/jats:p>","DOI":"10.1107\/s2414314624004978","type":"journal-article","created":{"date-parts":[[2024,5,29]],"date-time":"2024-05-29T06:21:28Z","timestamp":1716963688000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["(2,5-Dimethylimidazole){\n                    <i>N<\/i>\n                    ,\n                    <i>N<\/i>\n                    \u2032,\n                    <i>N<\/i>\n                    \u2032\u2032,\n                    <i>N<\/i>\n                    \u2032\u2032\u2032-[porphyrin-5,10,15,20-tetrayltetra(2,1-phenylene)]tetrakis(pyridine-3-carboxamide)}manganese(II) chlorobenzene disolvate"],"prefix":"10.1107","volume":"9","author":[{"given":"Jun","family":"Yang","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05qbk4x57","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cuijuan","family":"Zhang","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05qbk4x57","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaxiang","family":"Chu","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/05qbk4x57","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,6,4]]},"reference":[{"key":"hb4469_bb1","unstructured":"Bruker (2014). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"hb4469_bb2","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"hb4469_bb3","doi-asserted-by":"crossref","first-page":"283","DOI":"10.1021\/ic00171a006","volume":"23","author":"Gunter","year":"1984","journal-title":"Inorg. Chem."},{"key":"hb4469_bb4","doi-asserted-by":"crossref","first-page":"2557","DOI":"10.1021\/ja00450a025","volume":"99","author":"Kirner","year":"1977","journal-title":"J. Am. Chem. Soc."},{"key":"hb4469_bb5","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"hb4469_bb6","doi-asserted-by":"crossref","first-page":"3774","DOI":"10.1021\/acs.biochem.6b00253","volume":"55","author":"Krishna Deepak","year":"2016","journal-title":"Biochemistry"},{"key":"hb4469_bb7","doi-asserted-by":"crossref","first-page":"6729","DOI":"10.1021\/ja00542a011","volume":"102","author":"Landrum","year":"1980","journal-title":"J. Am. Chem. Soc."},{"key":"hb4469_bb8","doi-asserted-by":"crossref","first-page":"111068","DOI":"10.1016\/j.dyepig.2022.111068","volume":"211","author":"Liang","year":"2023","journal-title":"Dyes Pigments"},{"key":"hb4469_bb9","doi-asserted-by":"crossref","first-page":"5799","DOI":"10.1021\/ja00459a045","volume":"99","author":"Nappa","year":"1977","journal-title":"J. Am. Chem. Soc."},{"key":"hb4469_bb10","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"hb4469_bb11","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"hb4469_bb12","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1016\/j.dyepig.2018.09.058","volume":"162","author":"Yao","year":"2019","journal-title":"Dyes Pigments"},{"key":"hb4469_bb13","doi-asserted-by":"crossref","first-page":"9382","DOI":"10.1039\/C5DT00685F","volume":"44","author":"Yu","year":"2015","journal-title":"Dalton Trans."}],"container-title":["IUCrData"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2024\/06\/00\/hb4469\/hb4469.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2024\/06\/00\/hb4469\/hb4469.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,7,4]],"date-time":"2024-07-04T12:05:25Z","timestamp":1720094725000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2414314624004978"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,6,4]]},"references-count":13,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2024,6]]}},"alternative-id":["S2414314624004978"],"URL":"https:\/\/doi.org\/10.1107\/s2414314624004978","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2414314624004978\/hb4469sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314624004978\/hb4469Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314624004978\/hb4469sup3.docx","asserted-by":"subject"}]},"ISSN":["2414-3146"],"issn-type":[{"value":"2414-3146","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,6,4]]},"assertion":[{"value":"IUCrData","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/x"},"group":{"name":"general","label":"General"}},{"value":"data reports","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/x\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?hb4469","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"25 April 2024","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"27 May 2024","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"4 June 2024","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This data article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?hb4469"}},{"value":"\u00a9 2024 Yang\n                      et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}],"article-number":"x240497"}}