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The arene group is \u03b7<jats:sup>6<\/jats:sup> \u03c0-coordinated to the Ru atom with a centroid-to-metal distance of 1.6590\u2005(5)\u2005\u00c5, with the (<jats:italic>S<\/jats:italic>)-2-(4-isopropyl-4,5-dihydrooxazol-2-yl)phenolate chelate ligand forming a bite angle of 86.88\u2005(19)\u00b0 through its N and phenolate O atoms. The pseudo-octahedral geometry assumed by the complex is completed by a chloride ligand. The coordination of the optically pure bidentate ligand induces metal centered chirality onto the complex with a Flack parameter of \u22120.056.<\/jats:p>","DOI":"10.1107\/s241431462400720x","type":"journal-article","created":{"date-parts":[[2024,7,26]],"date-time":"2024-07-26T04:49:20Z","timestamp":1721969360000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["(\u03b7<sup>6<\/sup>-Benzene)chlorido[(<i>S<\/i>)-2-(4-isopropyl-4,5-dihydrooxazol-2-yl)phenolato]ruthenium(II)"],"prefix":"10.1107","volume":"9","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6873-5415","authenticated-orcid":true,"given":"Monsuru T.","family":"Kelani","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2304-6987","authenticated-orcid":true,"given":"Alfred","family":"Muller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Koop","family":"Lammertsma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,7,26]]},"reference":[{"key":"zl4075_bb1","unstructured":"Bruker (2010). 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