{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T17:05:26Z","timestamp":1785431126265,"version":"3.56.0"},"reference-count":33,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2024,9,30]],"date-time":"2024-09-30T00:00:00Z","timestamp":1727654400000},"content-version":"vor","delay-in-days":2,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,9,30]],"date-time":"2024-09-30T00:00:00Z","timestamp":1727654400000},"content-version":"tdm","delay-in-days":2,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2024,9,24]]},"published-print":{"date-parts":[[2024,9,28]]},"abstract":"<jats:p>\n                    A new triazole-based\n                    <jats:italic>N<\/jats:italic>\n                    -heterocyclic carbene Ir\n                    <jats:sup>I<\/jats:sup>\n                    cationic complex with a tetrafluoridoborate counter-anion and hemi-solvating dichloromethane, [Ir(C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    )(C\n                    <jats:sub>8<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    )(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>15<\/jats:sub>\n                    P)]BF\n                    <jats:sub>4<\/jats:sub>\n                    \u00b70.5CH\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    , has been synthesized and structurally characterized. There are two independent ion pairs in the asymmetric unit and one dichloromethane solvent molecule per two ion pairs. The cationic complex exhibits a distorted square-planar conformation around the Ir\n                    <jats:sup>I<\/jats:sup>\n                    atom, formed by a bidentate cycloocta-1,5,diene (COD) ligand, a triphenylphosphane ligand, and an\n                    <jats:italic>N<\/jats:italic>\n                    -heterocyclic carbene (NHC). There are several close non-standard H...F hydrogen-bonding interactions that orient the tetrafluoridoborate anions with respect to the Ir\n                    <jats:sup>I<\/jats:sup>\n                    complex molecules. The complex shows promising catalytic activity in transfer hydrogenation reactions. The structure was refined as a non-merohedral twin, and one of the COD molecules is statistically disordered.\n                  <\/jats:p>","DOI":"10.1107\/s2414314624009416","type":"journal-article","created":{"date-parts":[[2024,9,25]],"date-time":"2024-09-25T02:05:36Z","timestamp":1727229936000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["[(1,2,5,6-\u03b7)-Cycloocta-1,5-diene](1-ethyl-4-isobutyl-1,2,4-triazol-5-ylidene)(triphenylphosphane)iridium(I) tetrafluoridoborate dichloromethane hemisolvate"],"prefix":"10.1107","volume":"9","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-7159-1336","authenticated-orcid":true,"given":"Timothy G.","family":"Lerch","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02x2aj034","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4790-6980","authenticated-orcid":true,"given":"Michael","family":"Gau","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4817-3915","authenticated-orcid":true,"given":"Daniel R.","family":"Albert","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02x2aj034","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Edward","family":"Rajaseelan","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02x2aj034","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,9,30]]},"reference":[{"key":"tk4109_bb1","doi-asserted-by":"crossref","first-page":"3596","DOI":"10.1021\/om020338x","volume":"21","author":"Albrecht","year":"2002","journal-title":"Organometallics"},{"key":"tk4109_bb2","unstructured":"Castaldi, K. 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