{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T09:32:52Z","timestamp":1759743172558,"version":"3.32.0"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2024,10,21]],"date-time":"2024-10-21T00:00:00Z","timestamp":1729468800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2024,10,21]],"date-time":"2024-10-21T00:00:00Z","timestamp":1729468800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2024,10,9]]},"published-print":{"date-parts":[[2024,10,28]]},"abstract":"<jats:p>The molecular structure of the title compound, C<jats:sub>20<\/jats:sub>H<jats:sub>26<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> reveals non-co-planarity between the central formamidine backbone and each of the outer methoxy- and <jats:italic>i<\/jats:italic>-propyl- substituted benzene rings with dihedral angles of 7.88\u2005(15) and 81.17\u2005(15)\u00b0, respectively, indicating significant twists in the molecule. In the crystal, intermolecular C\u2014H...O interactions, forming an <jats:italic>R<\/jats:italic>\n                  <jats:sup>3<\/jats:sup>\n                  <jats:sub>4<\/jats:sub>(30) graph set, occur within a two-dimensional layer that extends along the <jats:italic>ac<\/jats:italic> plane.<\/jats:p>","DOI":"10.1107\/s241431462400988x","type":"journal-article","created":{"date-parts":[[2024,10,11]],"date-time":"2024-10-11T09:20:10Z","timestamp":1728638410000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["(<i>Z<\/i>)-<i>N<\/i>-(2,6-Diisopropylphenyl)-1-[(2-methoxyphenyl)amino]methanimine oxide"],"prefix":"10.1107","volume":"9","author":[{"given":"David O.","family":"Juma","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bernard","family":"Omondi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1968-381X","authenticated-orcid":true,"given":"Sizwe J.","family":"Zamisa","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wisdom","family":"Munzeiwa","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2024,10,21]]},"reference":[{"key":"tk4110_bb1","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1016\/0010-8545(94)80059-6","volume":"133","author":"Barker","year":"1994","journal-title":"Coord. Chem. Rev."},{"key":"tk4110_bb2","unstructured":"Bruker (2010). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"tk4110_bb3","doi-asserted-by":"crossref","first-page":"565","DOI":"10.1081\/DMR-120005643","volume":"34","author":"Clement","year":"2002","journal-title":"Drug Metab. Rev."},{"key":"tk4110_bb4","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"tk4110_bb5","doi-asserted-by":"crossref","first-page":"141","DOI":"10.1002\/(SICI)1099-0690(199901)1999:1<141::AID-EJOC141>3.0.CO;2-U","author":"Giumanini","year":"1999","journal-title":"Eur. J. Org. Chem."},{"key":"tk4110_bb6","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"tk4110_bb7","doi-asserted-by":"crossref","first-page":"e4247","DOI":"10.1002\/aoc.4247","volume":"32","author":"Munzeiwa","year":"2018","journal-title":"Appl. Organomet. Chem."},{"key":"tk4110_bb8","doi-asserted-by":"crossref","first-page":"295","DOI":"10.1016\/j.poly.2017.09.029","volume":"138","author":"Munzeiwa","year":"2017","journal-title":"Polyhedron"},{"key":"tk4110_bb9","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"tk4110_bb10","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"tk4110_bb11","first-page":"7151","volume":"34","author":"Stojak","year":"2014","journal-title":"Anticancer Res."},{"key":"tk4110_bb12","doi-asserted-by":"crossref","first-page":"4459","DOI":"10.1039\/D1CE00458A","volume":"23","author":"Zamisa","year":"2021","journal-title":"CrystEngComm"}],"container-title":["IUCrData"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2024\/10\/00\/tk4110\/tk4110.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2024\/10\/00\/tk4110\/tk4110.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,12,20]],"date-time":"2024-12-20T11:36:38Z","timestamp":1734694598000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S241431462400988X"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,10,21]]},"references-count":12,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2024,10]]}},"alternative-id":["S241431462400988X"],"URL":"https:\/\/doi.org\/10.1107\/s241431462400988x","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S241431462400988X\/tk4110sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S241431462400988X\/tk4110Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S241431462400988X\/tk4110Isup3.cml","asserted-by":"subject"}]},"ISSN":["2414-3146"],"issn-type":[{"type":"electronic","value":"2414-3146"}],"subject":[],"published":{"date-parts":[[2024,10,21]]},"assertion":[{"value":"IUCrData","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/x"},"group":{"name":"general","label":"General"}},{"value":"data reports","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/x\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?tk4110","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"1 October 2024","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"9 October 2024","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"21 October 2024","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This data article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?tk4110"}},{"value":"\u00a9 2024 Juma et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}],"article-number":"x240988"}}