{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T15:56:53Z","timestamp":1785427013373,"version":"3.56.0"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2025,1,7]],"date-time":"2025-01-07T00:00:00Z","timestamp":1736208000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,1,7]],"date-time":"2025-01-07T00:00:00Z","timestamp":1736208000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Department of Biotechnology (DBT), New Delhi","award":["BT\/PR36476\/NNT\/28\/1723\/2020"],"award-info":[{"award-number":["BT\/PR36476\/NNT\/28\/1723\/2020"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2024,12,23]]},"published-print":{"date-parts":[[2025,1,28]]},"abstract":"<jats:p>\n                    The title compound, [RuCl(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    )(C\n                    <jats:sub>14<\/jats:sub>\n                    H\n                    <jats:sub>10<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )]BF\n                    <jats:sub>4<\/jats:sub>\n                    or [Ru(\u03b7\n                    <jats:sup>6<\/jats:sup>\n                    -benzene)(\n                    <jats:italic>L<\/jats:italic>\n                    )Cl]\n                    <jats:sup>+<\/jats:sup>\n                    BF\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    [where\n                    <jats:italic>L<\/jats:italic>\n                    denotes the 2-(pyridin-2-yl)quinoline ligand], crystallizes in the monoclinic space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>c<\/jats:italic>\n                    . The coordination environment around Ru\n                    <jats:sup>II<\/jats:sup>\n                    is best described as pseudo-octahedral, resembling the familiar half-sandwich \u2018three-legged piano-stool\u2019 shape. In the coordination sphere, the \u03b7\n                    <jats:sup>6<\/jats:sup>\n                    -binding benzene ligand coordinates with the central Ru\n                    <jats:sup>II<\/jats:sup>\n                    atom occupying the \u2018seat\u2019 of the stool with a metal-to-centroid distance of 1.695\u2005(17)\u2005\u00c5, while the chelate ligand\n                    <jats:italic>L<\/jats:italic>\n                    coordinates with its N atoms and, together with the Cl ligand, defines the \u2018legs\u2019 of the stool. Apart from Coulombic forces, C\u2014H...F and C\u2014H...Cl hydrogen-bonding interactions consolidate the crystal packing.\n                  <\/jats:p>","DOI":"10.1107\/s2414314624012409","type":"journal-article","created":{"date-parts":[[2025,1,1]],"date-time":"2025-01-01T04:48:17Z","timestamp":1735706897000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["(\u03b7\n                    <sup>6<\/sup>\n                    -Benzene)chlorido[2-(pyridin-2-yl)quinoline-\u03ba\n                    <sup>2<\/sup>\n                    <i>N<\/i>\n                    ,\n                    <i>N<\/i>\n                    \u2032]ruthenium(II) tetrafluoridoborate"],"prefix":"10.1107","volume":"10","author":[{"given":"Manikandan","family":"Varadhan","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03ytqnm28","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ibanpynhunlang","family":"Passi","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/055m2tx54","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thangaraja","family":"Chinnathangavel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2561-8387","authenticated-orcid":true,"given":"Venugopal","family":"Rajendiran","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03ytqnm28","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,1,7]]},"reference":[{"key":"wm4225_bb1","unstructured":"Agilent (2012). 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