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In the resulting zigzag chains, the molecules are related to each other by mirror planes (<jats:italic>m<\/jats:italic>) and twofold rotation axes (2), both perpendicular to the propagation plane, while translation is realized <jats:italic>via<\/jats:italic> a glide plane in direction of the crystallographic <jats:italic>c<\/jats:italic> axis, a combination of symmetry elements unique in the structural chemistry of diorganotin(IV) dihalides and pseudohalides, <jats:italic>R<\/jats:italic>\n                  <jats:sub>2<\/jats:sub>Sn<jats:italic>X<\/jats:italic>\n                  <jats:sub>2<\/jats:sub> with <jats:italic>X<\/jats:italic> = Hal or NCS. Its characteristics are subsumed in the term <jats:italic>Am<\/jats:italic>2<jats:italic>c<\/jats:italic> for this kind of intermolecular association pattern. 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