{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,3,14]],"date-time":"2025-03-14T04:11:24Z","timestamp":1741925484846,"version":"3.38.0"},"reference-count":15,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2025,2,7]],"date-time":"2025-02-07T00:00:00Z","timestamp":1738886400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,2,7]],"date-time":"2025-02-07T00:00:00Z","timestamp":1738886400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2025,1,29]]},"published-print":{"date-parts":[[2025,2,28]]},"abstract":"<jats:p>The title compound, {[Ni<jats:sub>5<\/jats:sub>(C<jats:sub>2<\/jats:sub>H<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>8<\/jats:sub>(OH)<jats:sub>2<\/jats:sub>]\u00b72.60H<jats:sub>2<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> or [Ni<jats:sub>5<\/jats:sub>(OAc)<jats:sub>8<\/jats:sub>(OH)<jats:sub>2<\/jats:sub>]\u00b72.60H<jats:sub>2<\/jats:sub>O (OAc is the acetate anion, C<jats:sub>2<\/jats:sub>H<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>), represents a hydrated basic acetate. Its asymmetric unit comprises half of the formula unit, with one of the three unique Ni<jats:sup>II<\/jats:sup> cations situated at an inversion centre. The Ni<jats:sup>II<\/jats:sup> atoms are in octahedral coordination environments by O atoms of the acetato ligands and by the basic OH group. The different kinds of bridging modes (\u03bc<jats:sub>2<\/jats:sub>, 2\u00d7\u03bc<jats:sub>3<\/jats:sub>, and \u03bc<jats:sub>4<\/jats:sub> for the acetato ligands; \u03bc<jats:sub>3<\/jats:sub> for the OH group) lead to the formation of a framework structure with hydrophobic channels extending parallel to the main crystallographic axes. Disordered water molecules are situated in pockets close to the OH groups and are held in place by hydrogen-bonding interactions.<\/jats:p>","DOI":"10.1107\/s2414314625000823","type":"journal-article","created":{"date-parts":[[2025,1,30]],"date-time":"2025-01-30T11:09:08Z","timestamp":1738235348000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Poly[[bis(\u03bc<sub>4<\/sub>-acetato-\u03ba<sup>4<\/sup>\n                  <i>O<\/i>:<i>O<\/i>:<i>O<\/i>\u2032:<i>O<\/i>\u2032)tetrakis(\u03bc<sub>3<\/sub>-acetato-\u03ba<sup>3<\/sup>\n                  <i>O<\/i>:<i>O<\/i>:<i>O<\/i>\u2032)bis(\u03bc<sub>2<\/sub>-acetato-\u03ba<sup>2<\/sup>\n                  <i>O<\/i>:<i>O<\/i>\u2032)bis(\u03bc<sub>3<\/sub>-hydroxido)pentanickel(II)] 2.60-hydrate]"],"prefix":"10.1107","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-7149-7310","authenticated-orcid":true,"given":"Maximilian","family":"Pfeiffer","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Berthold","family":"St\u00f6ger","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5235-9910","authenticated-orcid":true,"given":"Matthias","family":"Weil","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2025,2,7]]},"reference":[{"key":"bt4163_bb1","doi-asserted-by":"crossref","first-page":"787","DOI":"10.1107\/S2053229624010672","volume":"80","author":"Abrahams","year":"2024","journal-title":"Acta Cryst. 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