{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,3,14]],"date-time":"2025-03-14T04:11:19Z","timestamp":1741925479416,"version":"3.38.0"},"reference-count":25,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2025,2,28]],"date-time":"2025-02-28T00:00:00Z","timestamp":1740700800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,2,28]],"date-time":"2025-02-28T00:00:00Z","timestamp":1740700800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2025,2,25]]},"published-print":{"date-parts":[[2025,2,28]]},"abstract":"<jats:p>In the title compound, C<jats:sub>27<\/jats:sub>H<jats:sub>36<\/jats:sub>O<jats:sub>5<\/jats:sub>, the dihedral angles between the planes of the benzene ring and the cyclohexenone rings are 60.87\u2005(10) and 65.04\u2005(10)\u00b0, while the dihedral angle between the mean planes of the two cyclohexenone rings is 39.33\u2005(10)\u00b0. Each cyclohexenone ring has a carbon atom bonded to two methyl groups, which acts as the flap atom, resulting in an envelope conformation. The opposite orientation of the hydroxy and carbonyl oxygen atoms allows for the formation of two intramolecular O\u2014H...O hydrogen bonds and C\u2014H...\u03c0 (ring) interactions also help to establish the molecular conformation.<\/jats:p>","DOI":"10.1107\/s2414314625001804","type":"journal-article","created":{"date-parts":[[2025,2,28]],"date-time":"2025-02-28T08:38:58Z","timestamp":1740731938000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["2,2\u2032-[(4-Butoxyphenyl)methylene]bis(3-hydroxy-5,5-dimethylcyclohex-2-en-1-one)"],"prefix":"10.1107","volume":"10","author":[{"given":"N.","family":"Suresh Babu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"S.","family":"Anbu Chudar Azhagan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"B.","family":"Loganathan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"V.","family":"Sughanya","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"J.","family":"Ayyappan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2025,2,28]]},"reference":[{"key":"vm4064_bb1","doi-asserted-by":"crossref","first-page":"S1","DOI":"10.1039\/p298700000s1","volume":"2","author":"Allen","year":"1987","journal-title":"J. Chem. Soc. Perkin Trans."},{"key":"vm4064_bb2","unstructured":"Bruker (2016). APEX3 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"vm4064_bb3","doi-asserted-by":"crossref","first-page":"2","DOI":"10.1021\/jm940845j","volume":"39","author":"Cottam","year":"1996","journal-title":"J. Med. Chem."},{"key":"vm4064_bb4","doi-asserted-by":"crossref","first-page":"1354","DOI":"10.1021\/ja00839a011","volume":"97","author":"Cremer","year":"1975","journal-title":"J. Am. Chem. Soc."},{"key":"vm4064_bb5","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1016\/0223-5234(88)90182-1","volume":"23","author":"Dimmock","year":"1988","journal-title":"Eur. J. Med. Chem."},{"key":"vm4064_bb6","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Cryst."},{"key":"vm4064_bb7","doi-asserted-by":"crossref","first-page":"4383","DOI":"10.1016\/j.tetlet.2007.04.088","volume":"48","author":"Hilderbrand","year":"2007","journal-title":"Tetrahedron Lett."},{"key":"vm4064_bb8","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1021\/jo01171a014","volume":"11","author":"Horning","year":"1946","journal-title":"J. Org. Chem."},{"key":"vm4064_bb10","doi-asserted-by":"crossref","first-page":"3753","DOI":"10.1016\/S0040-4020(03)00554-4","volume":"59","author":"Kaupp","year":"2003","journal-title":"Tetrahedron"},{"key":"vm4064_bb11","doi-asserted-by":"crossref","first-page":"436","DOI":"10.1107\/S2056989023003171","volume":"79","author":"Khalilov","year":"2023","journal-title":"Acta Cryst. E"},{"key":"vm4064_bb12","doi-asserted-by":"crossref","first-page":"110735","DOI":"10.1016\/j.dyepig.2022.110735","volume":"208","author":"Khan","year":"2023","journal-title":"Dyes Pigments"},{"key":"vm4064_bb13","doi-asserted-by":"crossref","first-page":"683","DOI":"10.1042\/bj2580683","volume":"258","author":"Knight","year":"1989","journal-title":"Biochem. J."},{"key":"vm4064_bb14","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"vm4064_bb15","doi-asserted-by":"crossref","first-page":"132683","DOI":"10.1016\/j.molstruc.2022.132683","volume":"1259","author":"Lakhrissi","year":"2022","journal-title":"J. Mol. Struct."},{"key":"vm4064_bb16","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1107\/S1600576719014092","volume":"53","author":"Macrae","year":"2020","journal-title":"J. Appl. Cryst."},{"key":"vm4064_bb17","doi-asserted-by":"crossref","first-page":"4320","DOI":"10.1007\/s10904-022-02448-0","volume":"32","author":"Majumdar","year":"2022","journal-title":"J. Inorg. Organomet. Polym."},{"key":"vm4064_bb18","doi-asserted-by":"crossref","first-page":"3222","DOI":"10.1021\/cm970587p","volume":"9","author":"Pohlers","year":"1997","journal-title":"Chem. Mater."},{"key":"vm4064_bb19","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"vm4064_bb20","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"vm4064_bb21","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1107\/S2056989019016244","volume":"76","author":"Spek","year":"2020","journal-title":"Acta Cryst. E"},{"key":"vm4064_bb22","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1107\/S2056989019017018","volume":"76","author":"Steiger","year":"2020","journal-title":"Acta Cryst. E"},{"key":"vm4064_bb23","doi-asserted-by":"crossref","first-page":"o2875","DOI":"10.1107\/S1600536812037853","volume":"68","author":"Sughanya","year":"2012","journal-title":"Acta Cryst. E"},{"key":"vm4064_bb24","doi-asserted-by":"crossref","first-page":"o2638","DOI":"10.1107\/S1600536812033934","volume":"68","author":"Sureshbabu","year":"2012","journal-title":"Acta Cryst. E"},{"key":"vm4064_bb25","doi-asserted-by":"crossref","first-page":"o1690","DOI":"10.1107\/S1600536813028584","volume":"69","author":"Sureshbabu","year":"2013","journal-title":"Acta Cryst. E"},{"key":"vm4064_bb26","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."}],"container-title":["IUCrData"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2025\/02\/00\/vm4064\/vm4064.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2025\/02\/00\/vm4064\/vm4064.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,3,13]],"date-time":"2025-03-13T06:48:07Z","timestamp":1741848487000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2414314625001804"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,2,28]]},"references-count":25,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2025,2]]}},"alternative-id":["S2414314625001804"],"URL":"https:\/\/doi.org\/10.1107\/s2414314625001804","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2414314625001804\/vm4064sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314625001804\/vm4064Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314625001804\/vm4064Isup3.cml","asserted-by":"subject"}]},"ISSN":["2414-3146"],"issn-type":[{"type":"electronic","value":"2414-3146"}],"subject":[],"published":{"date-parts":[[2025,2,28]]},"assertion":[{"value":"IUCrData","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/x"},"group":{"name":"general","label":"General"}},{"value":"data reports","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/x\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?vm4064","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"14 February 2025","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"25 February 2025","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"28 February 2025","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This data article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?vm4064"}},{"value":"\u00a9 2025 Suresh Babu et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}],"article-number":"x250180"}}