{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T15:56:55Z","timestamp":1785427015447,"version":"3.56.0"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2025,6,20]],"date-time":"2025-06-20T00:00:00Z","timestamp":1750377600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,6,20]],"date-time":"2025-06-20T00:00:00Z","timestamp":1750377600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"the Algerian MESRS"},{"name":"the Algerian DGRSDT"},{"name":"the PRFU project","award":["B00L01UN190120230003"],"award-info":[{"award-number":["B00L01UN190120230003"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2025,6,2]]},"published-print":{"date-parts":[[2025,6,28]]},"abstract":"<jats:p>\n                    The asymmetric unit of the title compound, [Fe(C\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    ][C{C(CN)\n                    <jats:sub>2<\/jats:sub>\n                    }\n                    <jats:sub>3<\/jats:sub>\n                    ], contains an iron\u2013bipyridyl unit and one third of two crystallographic independent tris(dicyanomethylidene)methanediide units. As a result of crystallographic site symmetry the ratio of cations to anions is 1:1. The tris(2,2\u2032-bipyridine)iron(II) cation has threefold symmetry. The two crystallographic independent tris(dicyanomethylidene)methanediide ions are disordered over two atomic sites having equal occupancy. The anions have\n                    <jats:overline>3<\/jats:overline>\n                    symmetry. In the crystal, hydrogen bonds between cations and anions form complex layers parallel to (001). These are supplemented by hydrogen bonds perpendicular to the former, leading to a three-dimensional network.\n                  <\/jats:p>","DOI":"10.1107\/s2414314625005036","type":"journal-article","created":{"date-parts":[[2025,6,16]],"date-time":"2025-06-16T03:00:57Z","timestamp":1750042857000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Tris(2,2\u2032-bipyridine)iron(II) tris(dicyanomethylidene)methanediide"],"prefix":"10.1107","volume":"10","author":[{"given":"Said Abdelghafour","family":"Messalti","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02rzqza52","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9860-9310","authenticated-orcid":true,"given":"Fatima","family":"Setifi","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02rzqza52","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6984-6042","authenticated-orcid":true,"given":"Uwe","family":"B\u00f6hme","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8160-3852","authenticated-orcid":true,"given":"Zouaoui","family":"Setifi","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02rzqza52","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9777-2653","authenticated-orcid":true,"given":"Mohammad Hadi","family":"Al-Douh","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,6,20]]},"reference":[{"key":"bt4174_bb1","doi-asserted-by":"crossref","first-page":"1717","DOI":"10.1107\/S2056989018015426","volume":"74","author":"Addala","year":"2018","journal-title":"Acta Cryst. 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