{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,11]],"date-time":"2025-09-11T18:35:39Z","timestamp":1757615739855,"version":"3.44.0"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2025,8,21]],"date-time":"2025-08-21T00:00:00Z","timestamp":1755734400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2025,8,21]],"date-time":"2025-08-21T00:00:00Z","timestamp":1755734400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2025,8,7]]},"published-print":{"date-parts":[[2025,8,28]]},"abstract":"<jats:p>The title compound, di-\u03bc-hydroxido-bis[iodidodiphenyltin(IV)]\u20131,3-dimethylimidazolidin-2-one (1\/2), [Sn(C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub>I(OH)]\u00b72C<jats:sub>6<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>2<\/jats:sub>O, represents only the second example in the dimeric diorganotin(IV)-hydroxide-halide solvates [<jats:italic>R<\/jats:italic>\n                  <jats:sub>2<\/jats:sub>Sn(OH)<jats:italic>Hal<\/jats:italic>]<jats:sub>2<\/jats:sub>\u00b72<jats:italic>BB<\/jats:italic> with <jats:italic>Hal<\/jats:italic> = I. As is usual for this class of compound, dimerization takes place <jats:italic>via<\/jats:italic> the oxygen atoms of the hydroxyl groups and leads to a planar, centrosymmetric, four-membered Sn\u2014O ring of rhomboidal shape whose Sn\u2014O distances [2.024\u2005(2)\/2.174\u2005(2)\u2005\u00c5] are determined by the position (<jats:italic>axial<\/jats:italic> or <jats:italic>equatorial<\/jats:italic>) of the oxygen atom on the respective trigonal\u2013pyramidal coordinated tin atom while the bond angles are acute [70.74\u2005(8)\u00b0] at the tin atoms and obtuse [109.26\u2005(8)\u00b0] at the oxygen atoms.<\/jats:p>","DOI":"10.1107\/s2414314625007114","type":"journal-article","created":{"date-parts":[[2025,8,19]],"date-time":"2025-08-19T13:47:22Z","timestamp":1755611242000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Di-\u03bc-hydroxido-bis[iodidodiphenyltin(IV)]\u20131,3-dimethylimidazolidin-2-one (1\/2)"],"prefix":"10.1107","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1251-0783","authenticated-orcid":true,"given":"Hans","family":"Reuter","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2025,8,21]]},"reference":[{"key":"zl4086_bb1","first-page":"2S1","author":"Allen","year":"1987","journal-title":"J. Chem. Soc. Perkin Trans."},{"key":"zl4086_bb2","doi-asserted-by":"crossref","first-page":"245","DOI":"10.1080\/0095897021000050978","volume":"56","author":"Anacona","year":"2003","journal-title":"J. Coord. Chem."},{"key":"zl4086_bb3","doi-asserted-by":"crossref","first-page":"731","DOI":"10.1016\/j.jorganchem.2006.09.064","volume":"692","author":"Barba","year":"2007","journal-title":"J. Organomet. Chem."},{"key":"zl4086_bb4","unstructured":"Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"zl4086_bb5","unstructured":"Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"zl4086_bb6","doi-asserted-by":"crossref","first-page":"2832","DOI":"10.1039\/b801115j","author":"Cordero","year":"2008","journal-title":"Dalton Trans."},{"key":"zl4086_bb7","doi-asserted-by":"crossref","first-page":"133","DOI":"10.1016\/j.inoche.2010.10.004","volume":"14","author":"Di Nicola","year":"2011","journal-title":"Inorg. Chem. Commun."},{"key":"zl4086_bb8","doi-asserted-by":"crossref","first-page":"405","DOI":"10.1016\/0022-328X(88)80103-7","volume":"345","author":"Jones","year":"1988","journal-title":"J. Organomet. Chem."},{"key":"zl4086_bb9","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Cryst."},{"key":"zl4086_bb10","doi-asserted-by":"crossref","first-page":"m716","DOI":"10.1107\/S1600536809019758","volume":"65","author":"Lo","year":"2009","journal-title":"Acta Cryst. E"},{"key":"zl4086_bb11","doi-asserted-by":"crossref","first-page":"4420","DOI":"10.1021\/ic100034q","volume":"49","author":"Lundberg","year":"2010","journal-title":"Inorg. Chem."},{"key":"zl4086_bb21","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1107\/S1600576719014092","volume":"53","author":"Macrae","year":"2020","journal-title":"J. Appl. Cryst."},{"key":"zl4086_bb12","doi-asserted-by":"crossref","first-page":"385","DOI":"10.1002\/hlca.19820650141","volume":"65","author":"Mukhopadhyay","year":"1982","journal-title":"Helv. Chim. Acta"},{"key":"zl4086_bb13","doi-asserted-by":"crossref","first-page":"163","DOI":"10.1016\/0022-328X(85)87252-1","volume":"287","author":"Puff","year":"1985","journal-title":"J. Organomet. Chem."},{"key":"zl4086_bb14","doi-asserted-by":"crossref","first-page":"173","DOI":"10.1016\/0022-328X(89)85043-0","volume":"373","author":"Puff","year":"1989","journal-title":"J. Organomet. Chem."},{"key":"zl4086_bb15","doi-asserted-by":"crossref","unstructured":"Reuter, H. (2023). IUCrData 8, x230056.","DOI":"10.1107\/S2414314623000561"},{"key":"zl4086_bb16","doi-asserted-by":"crossref","first-page":"496","DOI":"10.1139\/cjc-2013-0517","volume":"92","author":"Reuter","year":"2014","journal-title":"Can. J. Chem."},{"key":"zl4086_bb17","doi-asserted-by":"crossref","first-page":"e202400091","DOI":"10.1002\/zaac.202400091","volume":"650","author":"Schr\u00f6der","year":"2024","journal-title":"Z. Anorg. Allg. Chem."},{"key":"zl4086_bb18","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"zl4086_bb19","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"zl4086_bb20","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."}],"container-title":["IUCrData"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2025\/08\/00\/zl4086\/zl4086.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/x\/issues\/2025\/08\/00\/zl4086\/zl4086.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T15:14:24Z","timestamp":1757085264000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2414314625007114"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,8,21]]},"references-count":21,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2025,8]]}},"alternative-id":["S2414314625007114"],"URL":"https:\/\/doi.org\/10.1107\/s2414314625007114","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2414314625007114\/zl4086sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2414314625007114\/zl4086Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2414-3146"],"issn-type":[{"type":"electronic","value":"2414-3146"}],"subject":[],"published":{"date-parts":[[2025,8,21]]},"assertion":[{"value":"IUCrData","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/x"},"group":{"name":"general","label":"General"}},{"value":"data reports","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/x\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?zl4086","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"31 July 2025","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"7 August 2025","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"21 August 2025","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This data article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?zl4086"}},{"value":"\u00a9 2025 Hans Reuter","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}],"article-number":"x250711"}}