{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,5]],"date-time":"2026-03-05T11:20:51Z","timestamp":1772709651923,"version":"3.50.1"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T00:00:00Z","timestamp":1771891200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T00:00:00Z","timestamp":1771891200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"crossref","award":["2021R1I1A3059982"],"award-info":[{"award-number":["2021R1I1A3059982"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100014188","name":"Ministry of Science and ICT","doi-asserted-by":"crossref","award":["RS-2022-00164805"],"award-info":[{"award-number":["RS-2022-00164805"]}],"id":[{"id":"10.13039\/501100014188","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2026,2,19]]},"published-print":{"date-parts":[[2026,2,28]]},"abstract":"<jats:p>\n                    The structure of the title compound, [Zn\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    (C\n                    <jats:sub>34<\/jats:sub>\n                    H\n                    <jats:sub>52<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    Si\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ], has been determined from synchrotron data, \u03bb = 0.70000\u2005\u00c5. The complete metallacyclic molecule is generated by crystallographic inversion symmetry, with the Zn\n                    <jats:sup>II<\/jats:sup>\n                    ion located in a general position. The 1,3-bis(dimethylsilyl-3-pyridine)propane ligand binds to two zinc(II) ions in a horse-shoe fashion, resulting in formation of a dimeric 24-membered macrocycle. The Zn\n                    <jats:sup>II<\/jats:sup>\n                    ion has a typical tetrahedral geometry\n                    <jats:italic>via<\/jats:italic>\n                    two iodide ions and two N donor atoms of the 1,3-bis(dimethylsilyl-3-pyridine)propane ligand. The macrocyclic dimers interact\n                    <jats:italic>via<\/jats:italic>\n                    weak interactions [I...H (H\n                    <jats:sub>3<\/jats:sub>\n                    CSi-) = 3.08, 3.27\u2005\u00c5].\n                  <\/jats:p>","DOI":"10.1107\/s2414314626001835","type":"journal-article","created":{"date-parts":[[2026,2,20]],"date-time":"2026-02-20T10:32:57Z","timestamp":1771583577000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Bis{\u03bc-1,3-bis[dimethyl(pyridin-3-yl)silyl]propane-\u03ba\n                    <sup>2<\/sup>\n                    <i>N<\/i>\n                    :\n                    <i>N<\/i>\n                    \u2032}bis[diiodidozinc(II)] from synchrotron data"],"prefix":"10.1107","volume":"11","author":[{"given":"Jiyeong","family":"Song","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dongwon","family":"Kim","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Young-A","family":"Lee","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2026,2,24]]},"reference":[{"key":"zl4091_bb1","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. 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Crystal Impact GbR, Bonn, Germany."},{"key":"zl4091_bb8","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"zl4091_bb9","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"zl4091_bb10","doi-asserted-by":"crossref","first-page":"594","DOI":"10.1002\/bkcs.70021","volume":"46","author":"Shin","year":"2025","journal-title":"Bull. Korean Chem. Soc."},{"key":"zl4091_bb11","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. 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