{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T16:57:47Z","timestamp":1775581067662,"version":"3.50.1"},"reference-count":15,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2026,3,3]],"date-time":"2026-03-03T00:00:00Z","timestamp":1772496000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,3,3]],"date-time":"2026-03-03T00:00:00Z","timestamp":1772496000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"the Ministry of Education and Science of Ukraine","award":["26BF037-01"],"award-info":[{"award-number":["26BF037-01"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2026,2,26]]},"published-print":{"date-parts":[[2026,3,28]]},"abstract":"<jats:p>\n                    The orthorhombic (space group\n                    <jats:italic>Pna<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    ) unit cell of the title compound, [CoCl\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>13<\/jats:sub>\n                    H\n                    <jats:sub>10<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00b7CH\n                    <jats:sub>3<\/jats:sub>\n                    OH\u00b7H\n                    <jats:sub>2<\/jats:sub>\n                    O, contains eight complex molecules, four\n                    <jats:italic>A<\/jats:italic>\n                    and four\n                    <jats:italic>B<\/jats:italic>\n                    , along with sixteen solvent molecules of crystallization. The two independent Co\n                    <jats:sup>II<\/jats:sup>\n                    atoms are coordinated by imine and pyridine N atoms from each of two neutral pyridinyliminobenzoic acids and two\n                    <jats:italic>cis<\/jats:italic>\n                    -chlorido ligands in a distorted octahedral coordination environment. In the crystal, the complex molecules pack loosely with the closest Co...Co separation exceeding 7.7\u2005\u00c5. The uncoordinated carboxylic groups on the ligands are presumably hydrogen-bonded to the solvent methanol and water molecules.\n                  <\/jats:p>","DOI":"10.1107\/s2414314626002154","type":"journal-article","created":{"date-parts":[[2026,2,27]],"date-time":"2026-02-27T10:42:46Z","timestamp":1772188966000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Dichloridobis(3-{[(pyridin-2-yl)methylidene]amino}benzoic acid-\u03ba\n                    <sup>2<\/sup>\n                    <i>N<\/i>\n                    ,\n                    <i>N<\/i>\n                    \u2032)cobalt(II) methanol monosolvate monohydrate"],"prefix":"10.1107","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4315-8399","authenticated-orcid":true,"given":"Olga Yu.","family":"Vassilyeva","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1834-3020","authenticated-orcid":true,"given":"Vladimir N.","family":"Kokozay","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1515-6636","authenticated-orcid":true,"given":"Brian W.","family":"Skelton","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2026,3,3]]},"reference":[{"key":"tk4120_bb1","first-page":"435","volume":"27","author":"Altomare","year":"1994","journal-title":"J. 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