{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T22:59:40Z","timestamp":1792709980512,"version":"4.5.0"},"reference-count":9,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2026,3,11]],"date-time":"2026-03-11T00:00:00Z","timestamp":1773187200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,3,11]],"date-time":"2026-03-11T00:00:00Z","timestamp":1773187200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2026,3,3]]},"published-print":{"date-parts":[[2026,3,28]]},"abstract":"<jats:p>\n                    The title compound, C\n                    <jats:sub>22<\/jats:sub>\n                    H\n                    <jats:sub>16<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    , crystallizes in the monoclinic space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>c<\/jats:italic>\n                    with two independent molecules,\n                    <jats:italic>A<\/jats:italic>\n                    and\n                    <jats:italic>B<\/jats:italic>\n                    , in the asymmetric unit. The isoxazole ring is inclined to the pyridine ring system, the indoline ring, and the phenyl ring by 8.00\u2005(10), 70.93\u2005(10), 35.89\u2005(12), respectively, \u00b0 for molecule\n                    <jats:italic>A<\/jats:italic>\n                    ,and 4.24\u2005(10), 84.62\u2005(9),30.02\u2005(11)\u00b0 for molecule\n                    <jats:italic>B<\/jats:italic>\n                    . In the crystal, molecules are linked by C\u2014H...O and C\u2014H...N interactions, forming layers parallel to the (100) plane. In addition \u03c0\u2013\u03c0 interactions with centroid-to-centroid distances of 3.8057\u2005(12)\u2005\u00c5 and a series of C\u2014H...\u03c0 interactions help to consolidate the packing in a three-dimensional architecture within the crystal. Additional electron density was localized in voids (398\u2005\u00c5\n                    <jats:sup>3<\/jats:sup>\n                    solvent accessible volume) summing up to 92 electrons, which corresponds to approximately 3.5 molecules of ethanol. The given chemical formula and other crystal data do not take into account the solvent.\n                  <\/jats:p>","DOI":"10.1107\/s2414314626002324","type":"journal-article","created":{"date-parts":[[2026,3,5]],"date-time":"2026-03-05T14:08:48Z","timestamp":1772719728000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["1,3\u2032-Dimethyl-2-oxo-6\u2032-phenyl-7\u2032\n                    <i>H<\/i>\n                    -spiro[indoline-3,4\u2032-isoxazolo[5,4-\n                    <i>b<\/i>\n                    ]pyridine]-5\u2032-carbonitrile"],"prefix":"10.1107","volume":"11","author":[{"given":"S.","family":"Logalakshmi","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Panneerselvam","family":"Yuvaraj","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/02p8nt844","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dhruba Jyoti","family":"Boruah","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/053rcsq61","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"R.","family":"Raja","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"G.","family":"Puthilibai","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,3,11]]},"reference":[{"key":"vm4076_bb1","unstructured":"Bruker (2016). 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