{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,3]],"date-time":"2026-07-03T15:20:48Z","timestamp":1783092048966,"version":"3.54.6"},"reference-count":9,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T00:00:00Z","timestamp":1782777600000},"content-version":"vor","delay-in-days":2,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T00:00:00Z","timestamp":1782777600000},"content-version":"tdm","delay-in-days":2,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2026,6,25]]},"published-print":{"date-parts":[[2026,6,28]]},"abstract":"<jats:p>\n                    The title molecular salt, C\n                    <jats:sub>24<\/jats:sub>\n                    H\n                    <jats:sub>23<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>+.<\/jats:sup>\n                    C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>7<\/jats:sub>\n                    , consists of a 2,4,5-tris(4-methylphenyl)-1\n                    <jats:italic>H<\/jats:italic>\n                    -imidazol-3-ium cation and a 2,4,6-trinitrophenolate anion. The compound crystallizes in the monoclinic space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>c<\/jats:italic>\n                    . In the crystal, the cation and anion are linked by N\u2014H...O hydrogen bonds. One imidazolium N\u2014H group forms a hydrogen bond to the phenolate oxygen atom of the picrate anion, while the second N\u2014H group forms an intermolecular hydrogen bond to a disordered nitro oxygen atom of a symmetry-related picrate anion. The crystal packing is further consolidated by several offset \u03c0\u2013\u03c0 stacking contacts between neighbouring aromatic rings, with centroid\u2013centroid separations in the range 3.560\u2005(2)\u20133.872\u2005(2)\u2005\u00c5. The oxygen atoms of the nitro groups of the picrate anion are disordered over two sets of positions and were refined with split occupancies using suitable geometric and displacement-parameter restraints.\n                  <\/jats:p>","DOI":"10.1107\/s2414314626006711","type":"journal-article","created":{"date-parts":[[2026,6,26]],"date-time":"2026-06-26T09:48:18Z","timestamp":1782467298000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["2,4,5-Tris(4-methylphenyl)-1\n                    <i>H<\/i>\n                    -imidazol-3-ium 2,4,6-trinitrophenolate"],"prefix":"10.1107","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5251-9654","authenticated-orcid":true,"given":"Peter","family":"Solo","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1508-801X","authenticated-orcid":true,"given":"Michael","family":"Pillay","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tharsius Raja","family":"William Raja","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,6,30]]},"reference":[{"key":"bt4202_bb1","unstructured":"Bruker (2018). 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