{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T11:10:45Z","timestamp":1788779445547,"version":"build-2803163510"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T00:00:00Z","timestamp":1786665600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T00:00:00Z","timestamp":1786665600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2026,8,3]]},"published-print":{"date-parts":[[2026,8,28]]},"abstract":"<jats:p>\n                    The title compound, [Ag(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>13<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    P)\n                    <jats:sub>4<\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    P)](CO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    or [Ag(PTAH)\n                    <jats:sub>3<\/jats:sub>\n                    (PTA)](CO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    , is a discrete cationic silver(I) complex composed of one neutral 1,3,5-triaza-7-phosphaadamantane (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    P; PTA) ligand and three monoprotonated PTAH\n                    <jats:sup>+<\/jats:sup>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>13<\/jats:sub>\n                    N\n                    <jats:sub>3<\/jats:sub>\n                    P\n                    <jats:sup>+<\/jats:sup>\n                    ) ligands coordinated to the silver center, resulting in an overall +4 charge balanced by two carbonate anions. The compound crystallizes in the rhombohedral\n                    <jats:italic>R<\/jats:italic>\n                    3 space group with the silver ion and PTA P atom lying on a crystallographic threefold axis, as does one of the carbonate C atoms. The silver ion adopts a tetrahedral geometry with P\u2014Ag\u2014P bond angles near the ideal 109\u00b0, and silver\u2013phosphorus bond distances of 2.4699\u2005(6) and 2.4683\u2005(11)\u2005\u00c5 for Ag\u2014P\n                    <jats:sub>PTA<\/jats:sub>\n                    and Ag\u2014P\n                    <jats:sub>PTAH<\/jats:sub>\n                    , respectively. The crystal packing features N\u2014H...O hydrogen bonds between the protonated N atoms of the PTAH ligands and the non-coordinating carbonate anions.\n                  <\/jats:p>","DOI":"10.1107\/s2414314626007935","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T09:46:52Z","timestamp":1785923212000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Tris(3,5-diaza-1-azonia-7-phosphaadamant-7-yl)(1,3,5-triaza-7-phospha-adamantane)silver(I) dicarbonate"],"prefix":"10.1107","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1968-381X","authenticated-orcid":true,"given":"Sizwe J.","family":"Zamisa","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9287-5960","authenticated-orcid":true,"given":"Adesola A.","family":"Adeleke","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8348-1353","authenticated-orcid":true,"given":"Olatunde S.","family":"Olatunji","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bernard","family":"Omondi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,8,14]]},"reference":[{"key":"hb4568_bb1","doi-asserted-by":"crossref","first-page":"6309","DOI":"10.1021\/acs.inorgchem.8b00227","volume":"57","author":"Armstrong","year":"2018","journal-title":"Inorg. 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