{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T21:00:23Z","timestamp":1791234023225,"version":"4.1.0"},"reference-count":18,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2026,8,21]]},"published-print":{"date-parts":[[2026,9,28]]},"abstract":"<jats:p>\n                    The title complex, [RuCl\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    )(C\n                    <jats:sub>21<\/jats:sub>\n                    H\n                    <jats:sub>33<\/jats:sub>\n                    P)] or (\u03b7\n                    <jats:sup>6<\/jats:sup>\n                    -C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    )((C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>11<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:sup>\n                      <jats:italic>i<\/jats:italic>\n                    <\/jats:sup>\n                    PrC\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    )P)RuCl\n                    <jats:sub>2<\/jats:sub>\n                    crystallizes in the space group\n                    <jats:italic>P<\/jats:italic>\n                    <jats:overline>1<\/jats:overline>\n                    with one molecule in the asymmetric unit. The Ru\n                    <jats:sup>II<\/jats:sup>\n                    atom is located at distances of 2.3830\u2005(7), 2.3925\u2005(8), 2.4269\u2005(8), and 1.6919\u2005(3)\u2005\u00c5 from the P, the two Cl ligands, and the centroid of the benzene molecule, respectively. A cone angle of 159\u00b0 was calculated for the steric pocket of the phosphane ligand. Positional disorder over two sets of sites in the methine and one of the methyl groups of the isopropyl substitutent resulted in a refined 0.528\u2005(5):0.472\u2005(5) ratio. The crystal packing is consolidated by non-classical C\u2014H...Cl interactions.\n                  <\/jats:p>","DOI":"10.1107\/s2414314626008710","type":"journal-article","created":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T14:46:51Z","timestamp":1787842011000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["(\u03b7\n                    <sup>6<\/sup>\n                    -Benzene)dichlorido[dicyclohexyl(4-isopropylphenyl)phosphane-\u03ba\n                    <i>P<\/i>\n                    ]ruthenium(II)"],"prefix":"10.1107","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6873-5415","authenticated-orcid":true,"given":"Monsuru T.","family":"Kelani","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4173-2550","authenticated-orcid":true,"given":"Eric C.","family":"Hosten","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2304-6987","authenticated-orcid":true,"given":"Alfred","family":"Muller","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9162-5783","authenticated-orcid":true,"given":"Koop","family":"Lammertsma","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,3]]},"reference":[{"key":"wm4255_bb1","unstructured":"Bruker (2010). 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