{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T20:59:53Z","timestamp":1791233993705,"version":"4.1.0"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["IUCrData","IUCr Data","International Union Crystallogr Data","Int Union Cryst Data"],"accepted":{"date-parts":[[2026,8,28]]},"published-print":{"date-parts":[[2026,9,28]]},"abstract":"<jats:p>\n                    The title compound, C\n                    <jats:sub>16<\/jats:sub>\n                    H\n                    <jats:sub>11<\/jats:sub>\n                    BrN\n                    <jats:sub>2<\/jats:sub>\n                    , is a Schiff base formed through the condensation reaction of 2-quinolinecarboxaldehyde with 4-bromoaniline. The C=N bond length of 1.282\u2005(2)\u2005\u00c5 is consistent with its double-bond character. The imine linkage adopts the\n                    <jats:italic>E<\/jats:italic>\n                    configuration, as indicated by the N\u2014C\u2014C\u2014N torsion angle of 174.27\u2005(14)\u00b0. This value also demonstrates that the quinoline ring and imine group are arranged in an almost coplanar manner. In contrast, the 4-bromophenyl ring is significantly twisted relative to the imine-quinoline plane, as indicated by the C\u2014N\u2014C\u2014C torsion angle of approximately 46.8\u2005(2)\u00b0. Intermolecular C\u2014H...\u03c0 interactions between quinolinyl and bromophenyl rings form a three-dimensional supramolecular network in the crystal packing.\n                  <\/jats:p>","DOI":"10.1107\/s2414314626008953","type":"journal-article","created":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T10:08:56Z","timestamp":1788257336000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["(\n                    <i>E<\/i>\n                    )-\n                    <i>N<\/i>\n                    -(4-Bromophenyl)-1-(quinolin-2-yl)methanimine"],"prefix":"10.1107","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1968-381X","authenticated-orcid":true,"given":"Sizwe J.","family":"Zamisa","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9287-5960","authenticated-orcid":true,"given":"Adesola A.","family":"Adeleke","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bernard","family":"Omondi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Olatunde S.","family":"Olatunji","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,3]]},"reference":[{"key":"bt4206_bb1","doi-asserted-by":"crossref","first-page":"1205","DOI":"10.3390\/molecules26051205","volume":"26","author":"Adeleke","year":"2021","journal-title":"Molecules"},{"key":"bt4206_bb2","doi-asserted-by":"crossref","first-page":"363","DOI":"10.1007\/s10534-022-00377-6","volume":"35","author":"Adeleke","year":"2022","journal-title":"Biometals"},{"key":"bt4206_bb3","doi-asserted-by":"crossref","first-page":"110451","DOI":"10.1016\/j.inoche.2023.110451","volume":"150","author":"Boulechfar","year":"2023","journal-title":"Inorg. 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