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The packing of the complex in the structure, resulting from the overlap at the carbonitrile groups of the complexes, results in a grid-like assembly with Ru...Ru diagonal distances of 17.0973\u2005(9) and 20.0289\u2005(5)\u2005\u00c5, and a near 50% calculated void volume.\n                  <\/jats:p>","DOI":"10.1107\/s2414314626009375","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T08:09:49Z","timestamp":1790323789000},"update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["<i>trans<\/i>\n                    -Dichloridotetrakis(pyridine-4-carbonitrile-\u03ba\n                    <i>N<\/i>\n                    )ruthenium(II) toluene hemisolvate"],"prefix":"10.1107","volume":"11","author":[{"given":"Frank S.","family":"Goodavish","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/052k56z27","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sebasti\u00e3o A.","family":"Martin","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/052k56z27","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9491-1571","authenticated-orcid":true,"given":"Eric W.","family":"Reinheimer","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5345-9697","authenticated-orcid":true,"given":"Bradley W.","family":"Smucker","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/052k56z27","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,25]]},"reference":[{"key":"bh4104_bb1","doi-asserted-by":"crossref","first-page":"732","DOI":"10.1021\/acs.jchemed.2c01211","volume":"100","author":"Abrahams","year":"2023","journal-title":"J. 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