{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,16]],"date-time":"2026-05-16T09:27:11Z","timestamp":1778923631870,"version":"3.51.4"},"reference-count":18,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2012,2,4]],"date-time":"2012-02-04T00:00:00Z","timestamp":1328313600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2012,2,4]],"date-time":"2012-02-04T00:00:00Z","timestamp":1328313600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2012,3,15]]},"abstract":"<jats:p>The title compound, C<jats:sub>48<\/jats:sub>H<jats:sub>20<\/jats:sub>F<jats:sub>19<\/jats:sub>N<jats:sub>4<\/jats:sub>O<jats:sub>3<\/jats:sub>P, prepared by the nucleophilic attack of triethyl phosphite on one of the 4-fluoro atoms of 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin, contains a single molecule in the asymmetric unit. The porphyrin unit is almost planar [largest non-H atom deviation\u00a0= 0.174\u2005(6)\u2005\u00c5], and has the planes of the neighbouring benzene rings oriented at angles ranging from 64.3\u2005(2) to 89.6\u2005(3)\u00b0 relative to the porphyrin core. The P=O group is almost coplanar with the attached benzene ring, subtending an angle of 4.0\u2005(3)\u00b0. Several weak supramolecular interactions, namely C\u2014H...\u03c0, C\u2014F...\u03c0, P=O...\u03c0, C\u2014H...(O,F) and F...F contacts, contribute to the crystal packing.<\/jats:p>","DOI":"10.1107\/s0108270112002934","type":"journal-article","created":{"date-parts":[[2012,2,2]],"date-time":"2012-02-02T14:25:36Z","timestamp":1328192736000},"page":"o104-o107","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["5-[4-(Diethoxyphosphoryl)-2,3,5,6-tetrafluorophenyl]-10,15,20-tris(pentafluorophenyl)porphyrin"],"prefix":"10.1107","volume":"68","author":[{"given":"Carla F.","family":"Pereira","sequence":"first","affiliation":[]},{"given":"Jos\u00e9 A.","family":"Fernandes","sequence":"additional","affiliation":[]},{"given":"Jo\u00e3o M. M.","family":"Rodrigues","sequence":"additional","affiliation":[]},{"given":"S\u00e9rgio M. F.","family":"Vilela","sequence":"additional","affiliation":[]},{"given":"Jo\u00e3o P. 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