{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,18]],"date-time":"2026-03-18T07:25:09Z","timestamp":1773818709649,"version":"3.50.1"},"reference-count":33,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2014,1,16]],"date-time":"2014-01-16T00:00:00Z","timestamp":1389830400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2014,1,16]],"date-time":"2014-01-16T00:00:00Z","timestamp":1389830400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr B Struct Sci Cryst Eng Mater","Acta Crystallogr B","Acta Crystallogr B Struct Sci","Acta Cryst B","Acta Cryst B Struct Sci Cryst Eng Mater","Acta Cryst Sect B","Acta Cryst Sect B Struct Sci Cryst Eng Mater","Acta Crystallogr Sect B","Acta Crystallogr Sect B Struct Sci Cryst Eng Mater","Acta Crystallogr Sect B Struct Sci"],"published-print":{"date-parts":[[2014,2,1]]},"abstract":"<jats:p>Three new crystalline metal-organic frameworks have been prepared from the reaction of uranyl nitrate with nitrilotris(methylphosphonic acid) [H<jats:sub>6<\/jats:sub>nmp, N(CH<jats:sub>2<\/jats:sub>PO<jats:sub>3<\/jats:sub>H<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>], 1,4-phenylenebis(methylene)diphosphonic acid [H<jats:sub>4<\/jats:sub>pmd, C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>(PO<jats:sub>3<\/jats:sub>H<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>], and (benzene-1,3,5-triyltris(methylene))triphosphonic acid [H<jats:sub>6<\/jats:sub>bmt, C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>(PO<jats:sub>3<\/jats:sub>H<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>]. Compound [(UO<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>F(H<jats:sub>3<\/jats:sub>nmp)(H<jats:sub>2<\/jats:sub>O)]\u00b74H<jats:sub>2<\/jats:sub>O (I) crystallizes in space group<jats:italic>C<\/jats:italic>2\/<jats:italic>c<\/jats:italic>, showing two crystallographically independent uranyl centres with pentagonal bipyramidal coordination geometries. While one metal centre is composed of a {(UO<jats:sub>2<\/jats:sub>)O<jats:sub>3<\/jats:sub>(\u03bc-F)}<jats:sub>2<\/jats:sub>dimer, the other comprises an isolated {(UO<jats:sub>2<\/jats:sub>)O<jats:sub>5<\/jats:sub>} polyhedron. Compound [(UO<jats:sub>2<\/jats:sub>)(H<jats:sub>2<\/jats:sub>pmd)] (II) crystallizes in space group<jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic>, showing a centrosymmetric uranyl centre with an octahedral {(UO<jats:sub>2<\/jats:sub>)O<jats:sub>4<\/jats:sub>} coordination geometry. Compound [(UO<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>(H<jats:sub>3<\/jats:sub>bmt)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]\u00b714H<jats:sub>2<\/jats:sub>O (III) crystallizes in space group P\\bar 1, showing two crystallographically independent uranyl centres. One uranyl centre is a {(UO<jats:sub>2<\/jats:sub>)O<jats:sub>5<\/jats:sub>} pentagonal bipyramid similar to that in (I), while the other is a {(UO<jats:sub>2<\/jats:sub>)O<jats:sub>4<\/jats:sub>} centrosymmetric octahedron similar to that in (II). Compounds (I) and (III) contain solvent-accessible volumes accounting for<jats:italic>ca<\/jats:italic>23.6 and 26.9% of their unit-cell volume, respectively. In (I) the cavity has a columnar shape and is occupied by disordered water molecules, while in (III) the cavity is a two-dimensional layer with more ordered water molecules. All compounds have been studied in the solid state using FT-IR spectroscopy. Topological studies show that compounds (I) and (III) are trinodal, with 3,6,6- and 4,4,6-connected networks, respectively. Compound (II) is instead a 4-connected uninodal network of the type<jats:bold>cds<\/jats:bold>.<\/jats:p>","DOI":"10.1107\/s2052520613034781","type":"journal-article","created":{"date-parts":[[2014,1,15]],"date-time":"2014-01-15T23:03:09Z","timestamp":1389826989000},"page":"28-36","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":15,"title":["Metal-organic frameworks based on uranyl and phosphonate ligands"],"prefix":"10.1107","volume":"70","author":[{"given":"Bernardo","family":"Monteiro","sequence":"first","affiliation":[]},{"given":"Jos\u00e9 A.","family":"Fernandes","sequence":"additional","affiliation":[]},{"given":"Cl\u00e1udia C. L.","family":"Pereira","sequence":"additional","affiliation":[]},{"given":"S\u00e9rgio M. F.","family":"Vilela","sequence":"additional","affiliation":[]},{"given":"Jo\u00e3o P. 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