{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,29]],"date-time":"2025-11-29T07:54:21Z","timestamp":1764402861048,"version":"3.37.3"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2018,5,30]],"date-time":"2018-05-30T00:00:00Z","timestamp":1527638400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2018,5,30]],"date-time":"2018-05-30T00:00:00Z","timestamp":1527638400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["SFRH\/BD\/84495\/2012","BIM-SGH\/CICECO-UA\/174-01\/2017","Green Homes-BOSCH (POCI-010247-FEDER-007678)","FCOMP-01-0124-FEDER-041282 (Ref. 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Chem.<\/jats:italic> \n                  <jats:bold>56<\/jats:bold>, 1193\u20131208], was constructed based solely on Er<jats:sup>3+<\/jats:sup> and on the polyphosphonic organic linker [1,1\u2032-biphenyl]-3,3\u2032,5,5\u2032-tetrakis(phosphonic acid) (H<jats:sub>8<\/jats:sub>btp). The present work describes our efforts to introduce lanthanide cations into the flexible network, demonstrating that, on the one hand, the compound can be obtained using three distinct experimental methods, <jats:italic>i.e.<\/jats:italic> hydro(solvo)thermal (Hy), microwave-assisted (MW) and one-pot (Op), and, on the other hand, that crystallite size can be approximately fine-tuned according to the method employed. MOF <jats:bold>I<\/jats:bold> contains hexacoordinated Er<jats:sup>3+<\/jats:sup> cations which are distributed in a zigzag inorganic chain running parallel to the [100] direction of the unit cell. The chains are, in turn, bridged by the anionic organic linker to form a three-dimensional 6,6-connected binodal network. This connectivity leads to the existence of one-dimensional channels (also running parallel to the [100] direction) filled with disordered and partially occupied water molecules of crystalization which are engaged in O\u2014H...O hydrogen-bonding interactions with the [Er(H<jats:sub>5<\/jats:sub>btp)] framework. Additional weak \u03c0\u2013\u03c0 interactions [intercentroid distance = 3.957\u2005(7)\u2005\u00c5] exist between aromatic rings, which help to maintain the structural integrity of the network.<\/jats:p>","DOI":"10.1107\/s2053229618007374","type":"journal-article","created":{"date-parts":[[2018,5,30]],"date-time":"2018-05-30T15:18:17Z","timestamp":1527693497000},"page":"752-759","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Metal\u2013organic framework assembled from erbium and a tetrapodal polyphosphonic acid organic linker"],"prefix":"10.1107","volume":"74","author":[{"given":"Ricardo F.","family":"Mendes","sequence":"first","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8032-6489","authenticated-orcid":true,"given":"Ana D. G.","family":"Firmino","sequence":"additional","affiliation":[]},{"given":"Jo\u00e3o P. C.","family":"Tom\u00e9","sequence":"additional","affiliation":[]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2051-5645","authenticated-orcid":true,"given":"Filipe A.","family":"Almeida Paz","sequence":"additional","affiliation":[]}],"member":"329","published-online":{"date-parts":[[2018,5,30]]},"reference":[{"key":"lg3220_bb1","doi-asserted-by":"crossref","first-page":"3947","DOI":"10.1039\/c0ce00636j","volume":"13","author":"Alexandrov","year":"2011","journal-title":"CrystEngComm"},{"key":"lg3220_bb2","doi-asserted-by":"crossref","first-page":"9547","DOI":"10.1021\/acs.chemmater.7b03817","volume":"29","author":"Ananias","year":"2017","journal-title":"Chem. Mater."},{"key":"lg3220_bb3","doi-asserted-by":"crossref","first-page":"1195","DOI":"10.1107\/S0567740874004560","volume":"30","author":"Baur","year":"1974","journal-title":"Acta Cryst. B"},{"key":"lg3220_bb4","unstructured":"Blatov, V. A. & Shevchenko, A. P. (2006). TOPOS. Version 4.0 Professional (beta evaluation). Samara State University, Samara, Russia."},{"key":"lg3220_bb5","unstructured":"Brandenburg, K. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"lg3220_bb6","unstructured":"Bruker (2012). SAINT, APEX2 and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"lg3220_bb7","doi-asserted-by":"crossref","first-page":"6804","DOI":"10.1039\/C4CS00395K","volume":"44","author":"Chughtai","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"lg3220_bb8","unstructured":"Demadis, K. D. & Stavgianoudaki, N. (2012). Structural Diversity in Metal Phosphonate Frameworks: Impact on Applications, ch. 14, p. 438. London: The Royal Society of Chemistry."},{"key":"lg3220_bb9","doi-asserted-by":"crossref","first-page":"1805","DOI":"10.1039\/a809671f","author":"Distler","year":"1999","journal-title":"Dalton Trans."},{"key":"lg3220_bb10","doi-asserted-by":"crossref","first-page":"1051","DOI":"10.1039\/c39950001051","author":"Drumel","year":"1995","journal-title":"Chem. 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