{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T09:43:28Z","timestamp":1736847808677,"version":"3.33.0"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2016,11,15]],"date-time":"2016-11-15T00:00:00Z","timestamp":1479168000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2016,11,15]],"date-time":"2016-11-15T00:00:00Z","timestamp":1479168000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2016,12,1]]},"abstract":"<jats:p>A new metal\u2013organic framework compound, poly[[\u03bc<jats:sub>7<\/jats:sub>-dihydrogen (4,5-dicyano-1,2-phenylene)diphosphonato](oxonium)caesium], [Cs(C<jats:sub>8<\/jats:sub>H<jats:sub>4<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>6<\/jats:sub>P<jats:sub>2<\/jats:sub>)(H<jats:sub>3<\/jats:sub>O)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>(I), based on Cs<jats:sup>+<\/jats:sup>and the organic linker 4,5-dicyano-1,2-phenylene)bis(phosphonic acid, (H<jats:sub>4<\/jats:sub>cpp), containing two distinct coordinating functional groups, has been prepared by a simple diffusion method and its crystal structure is reported. The coordination polymeric structure is based on a CsO<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>complex unit comprising a monodentate hydronium cation, seven O-atom donors from two phosphonium groups of the (H<jats:sub>2<\/jats:sub>cpp)<jats:sup>2\u2212<\/jats:sup>ligand, and two N-atom donors from bridging cyano groups. The high level of connectivity from both the metal cation and the organic linker allow the formation of a compact and dense three-dimensional network without any crystallization solvent. Topologically (I) is a seven-connected uninodal network with an overall Sch\u00e4fli symbol of {4<jats:sup>17<\/jats:sup>.6<jats:sup>4<\/jats:sup>}. Metal cations form an undulating inorganic layer, which is linked by strong and highly directional O\u2014H...O hydrogen-bonding interactions. These metallic layers are, in turn, connected by the organic ligands along the [010] direction to form the overall three-dimensional framework structure.<\/jats:p>","DOI":"10.1107\/s2056989016016765","type":"journal-article","created":{"date-parts":[[2016,11,15]],"date-time":"2016-11-15T10:23:52Z","timestamp":1479205432000},"page":"1794-1798","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of a compact three-dimensional metal\u2013organic framework based on Cs<sup>+<\/sup>and (4,5-dicyano-1,2-phenylene)bis(phosphonic acid)"],"prefix":"10.1107","volume":"72","author":[{"given":"Ricardo F.","family":"Mendes","sequence":"first","affiliation":[]},{"given":"Nutalapati","family":"Venkatramaiah","sequence":"additional","affiliation":[]},{"given":"Jo\u00e3o P. 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