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To overcome these limitations, recent research incorporates zero\u2010dimensional carbon quantum dots (CQDs) as active nanomaterials. This review evaluates the physical, transport, and preservative synergies of CQD\/PVA composite matrices. Integrating uniform CQDs reduces matrix wettability through dense intermolecular hydrogen bonding with PVA hydroxyl groups, as evidenced by a 26.16% increase in water contact angle for 3% lemon peel\u2010derived CQDs. Furthermore, the impermeable nanoparticles introduce a classic tortuous\u2010path effect and act as heterogeneous nucleation sites, densifying the network and driving a profound 94.68% decrease in oxygen permeability with just 1% green tea\u2010derived CQDs. Beyond physical barrier optimization, embedded CQDs endow the matrix with robust multiwavelength UV\u2010blocking properties, potent antioxidant radical scavenging, and broad\u2010spectrum antimicrobial activity. These active functionalities effectively suppress oxygen\u2010dependent degradative enzymes, such as polyphenol oxidase, to halt browning, extending shelf life across fruit, bakery, and seafood models. 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