{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T12:01:32Z","timestamp":1788523292599,"version":"build-2803163510"},"reference-count":31,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2015,8,11]],"date-time":"2015-08-11T00:00:00Z","timestamp":1439251200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100002322","name":"CAPES","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003593","name":"CNPq","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003359","name":"Generalitat Valenciana","doi-asserted-by":"publisher","award":["PROMETEO 2010\/55"],"award-info":[{"award-number":["PROMETEO 2010\/55"]}],"id":[{"id":"10.13039\/501100003359","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Journal of Forensic Sciences"],"published-print":{"date-parts":[[2015,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>There is an increasing demand for herbal medicines in weight loss treatment. Some synthetic chemicals, such as sibutramine (<jats:styled-content style=\"fixed-case\">SB<\/jats:styled-content>), have been detected as adulterants in herbal formulations. In this study, two strategies using near infrared (<jats:styled-content style=\"fixed-case\">NIR<\/jats:styled-content>) spectroscopy have been developed to evaluate potential adulteration of herbal medicines with <jats:styled-content style=\"fixed-case\">SB<\/jats:styled-content>: a qualitative screening approach and a quantitative methodology based on multivariate calibration. Samples were composed by products commercialized as herbal medicines, as well as by laboratory adulterated samples. Spectra were obtained in the range of 14,000\u20134000 per cm. Using <jats:styled-content style=\"fixed-case\">PLS<\/jats:styled-content>\u2010<jats:styled-content style=\"fixed-case\">DA<\/jats:styled-content>, a correct classification of 100% was achieved for the external validation set. In the quantitative approach, the root mean squares error of prediction (<jats:styled-content style=\"fixed-case\">RMSEP<\/jats:styled-content>), for both <jats:styled-content style=\"fixed-case\">PLS<\/jats:styled-content> and <jats:styled-content style=\"fixed-case\">MLR<\/jats:styled-content> models, was 0.2%w\/w. The results prove the potential of <jats:styled-content style=\"fixed-case\">NIR<\/jats:styled-content> spectroscopy and multivariate calibration in quantifying sibutramine in adulterated herbal medicines samples.<\/jats:p>","DOI":"10.1111\/1556-4029.12884","type":"journal-article","created":{"date-parts":[[2015,8,11]],"date-time":"2015-08-11T10:39:05Z","timestamp":1439289545000},"page":"1199-1205","source":"Crossref","is-referenced-by-count":12,"title":["Near Infrared Spectroscopy Detection and Quantification of Herbal Medicines Adulterated with Sibutramine"],"prefix":"10.1111","volume":"60","author":[{"given":"Neirivaldo Cavalcante","family":"da Silva","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica Fundamental Universidade Federal de Pernambuco Recife PE Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ricardo Saldanha","family":"Honorato","sequence":"additional","affiliation":[{"name":"Departamento de Pol\u00edcia Federal Superintend\u00eancia Regional em Pernambuco Recife PE Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria Fernanda","family":"Pimentel","sequence":"additional","affiliation":[{"name":"Departamento de Engenharia Qu\u00edmica Universidade Federal de Pernambuco Recife PE Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Salvador","family":"Garrigues","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry University of Valencia Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria Luisa","family":"Cervera","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry University of Valencia Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miguel","family":"de la Guardia","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry University of Valencia Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,8,11]]},"reference":[{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.forsciint.2010.04.045"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0165-6147(00)01972-6"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.forsciint.2011.12.004"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2007.11.042"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0014-2999(02)01423-1"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpba.2012.02.004"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.forsciint.2006.02.052"},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpba.2005.12.015"},{"key":"e_1_2_5_10_1","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1093\/jaoac\/92.1.148","article-title":"Development and validation of a column high\u2010performance liquid chromatographic method for determination of sibutramine in capsules","volume":"92","author":"Diefenbach ICF","year":"2009","journal-title":"J AOAC Int"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1080\/02652030801946553"},{"key":"e_1_2_5_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2010.02.006"},{"key":"e_1_2_5_13_1","doi-asserted-by":"publisher","DOI":"10.1080\/19440041003705821"},{"key":"e_1_2_5_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpba.2011.08.028"},{"key":"e_1_2_5_15_1","doi-asserted-by":"publisher","DOI":"10.1366\/000370209787944217"},{"key":"e_1_2_5_16_1","doi-asserted-by":"publisher","DOI":"10.1590\/S0100-40422010000300031"},{"key":"e_1_2_5_17_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11418-011-0596-9"},{"key":"e_1_2_5_18_1","doi-asserted-by":"publisher","DOI":"10.1186\/1749-8546-3-9"},{"key":"e_1_2_5_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02897523"},{"key":"e_1_2_5_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2005.11.030"},{"key":"e_1_2_5_21_1","first-page":"793","article-title":"A validated specific reverse phase liquid chromatographic method for the estimation of sibutramine hydrochloride monohydrate in bulk drug and capsule dosage forms","volume":"1","author":"Suthar AP","year":"2009","journal-title":"Int J Chem Tech Res"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0169-7439(01)00119-8"},{"key":"e_1_2_5_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2005.03.025"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemolab.2004.03.004"},{"key":"e_1_2_5_25_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac200678030633"},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.vibspec.2012.04.011"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac00297a042"},{"key":"e_1_2_5_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0169-7439(03)00118-7"},{"key":"e_1_2_5_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac960862b"},{"key":"e_1_2_5_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac00087a718"},{"key":"e_1_2_5_31_1","doi-asserted-by":"publisher","DOI":"10.1590\/S0100-40422009000500034"},{"key":"e_1_2_5_32_1","first-page":"497","article-title":"Green analytical chemistry. TrAC\u2010Trend","volume":"27","author":"Armenta S","year":"2008","journal-title":"Anal Chem"}],"container-title":["Journal of Forensic Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1111%2F1556-4029.12884","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1111\/1556-4029.12884","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,17]],"date-time":"2023-09-17T07:10:38Z","timestamp":1694934638000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1111\/1556-4029.12884"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,8,11]]},"references-count":31,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2015,9]]}},"alternative-id":["10.1111\/1556-4029.12884"],"URL":"https:\/\/doi.org\/10.1111\/1556-4029.12884","archive":["Portico"],"relation":{},"ISSN":["0022-1198","1556-4029"],"issn-type":[{"value":"0022-1198","type":"print"},{"value":"1556-4029","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,8,11]]}}}