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By combining neuroimaging with smartphone\u2010based ecological momentary assessment (EMA), we questioned how biomarkers moderate inhibition deficits to predict use. Thus, we aimed to assess white matter integrity interaction with everyday inhibition deficits and related resting\u2010state network connectivity to identify multi\u2010dimensional predictors of substance use. Thirty\u2010eight patients treated for alcohol, cannabis or tobacco use disorder completed 1\u2009week of EMA to report substance use five times and complete Stroop inhibition testing twice daily. Before EMA tracking, participants underwent resting state functional MRI\u00a0and diffusion tensor imaging (DTI) scanning. Regression analyses were conducted between mean Stroop performances and whole\u2010brain fractional anisotropy (FA) in white matter. Moderation testing was conducted between mean FA within significant clusters as moderator and the link between momentary Stroop performance and use as outcome. 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In conclusion, compromised white matter structural integrity in anterior brain systems appears to underlie impairment in inhibitory control functional networks and compromised ability to refrain from substance use.<\/jats:p>","DOI":"10.1111\/adb.13400","type":"journal-article","created":{"date-parts":[[2024,5,6]],"date-time":"2024-05-06T03:54:05Z","timestamp":1714967645000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Multi\u2010level prediction of substance use: Interaction of white matter integrity, resting\u2010state connectivity and inhibitory control measured repeatedly in every\u2010day life"],"prefix":"10.1111","volume":"29","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7671-9941","authenticated-orcid":false,"given":"Valentine","family":"Chirokoff","sequence":"first","affiliation":[{"name":"Univ. 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