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Retrieved cores offer unique insight into an archive of Quaternary paleo\u2010environmental change, long\u2010term coral mound development, and the diagenetic alteration of these carbonate fabrics over time. To characterize biogeochemical carbon\u2013iron\u2013sulfur transformations in the mound sediments, the contents of dithionite\u2010 and HCl\u2010extractable iron phases, iron monosulfide and pyrite, and acid\u2010extractable calcium, magnesium, manganese, and strontium were determined. Additionally, the stable isotopic compositions of pore\u2010water sulfate and solid\u2010phase reduced sulfur compounds were analyzed. Sulfate penetrated through the mound sequence and into the underlying Miocene sediments, where a sulfate\u2013methane transition zone was identified. Small sulfate concentration decreases (&lt;7\u00a0m<jats:sc>m<\/jats:sc>) within the top 40\u00a0m of the mound suggested slow net rates of present\u2010day organoclastic sulfate reduction. Increasing \u03b4<jats:sup>34<\/jats:sup>S\u2010sulfate values due to microbial sulfate reduction mirrored the decrease in sulfate concentrations. This process was accompanied by oxygen isotope exchange with water that was indicated by increasing \u03b4<jats:sup>18<\/jats:sup>O\u2010sulfate values, reaching equilibrium with pore\u2010water at depth. Below 50\u00a0mbsf, sediment intervals with strong <jats:sup>34<\/jats:sup>S\u2010enriched imprints on chromium\u2010reducible sulfur (pyrite S), high degree\u2010of\u2010pyritization values, and semi\u2010lithified diagenetic carbonate\u2010rich layers characterized by poor coral preservation, were observed. These layers provided evidence for the occurrence of enhanced microbial sulfate\u2010reducing activity in the mound in the past during periods of rapid mound aggradation and subsequent intervals of non\u2010deposition or erosion when geochemical fronts remained stationary. During these periods, especially during the Early Pleistocene, elevated sulfate reduction rates facilitated the consumption of reducible iron oxide phases, coral dissolution, and the subsequent formation of carbonate cements.<\/jats:p>","DOI":"10.1111\/gbi.12147","type":"journal-article","created":{"date-parts":[[2015,6,11]],"date-time":"2015-06-11T02:16:21Z","timestamp":1433988981000},"page":"424-442","source":"Crossref","is-referenced-by-count":6,"title":["Linking sedimentary sulfur and iron biogeochemistry to growth patterns of a cold\u2010water coral mound in the Porcupine Basin, S.W. Ireland (IODP Expedition 307)"],"prefix":"10.1111","volume":"13","author":[{"given":"L. 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