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From this perspective, we studied an interval of the upper Bambu\u00ed Basin using sedimentologic, stratigraphic, and chemostratigraphic tools. The lower Cambrian Ja\u00edba Member of the uppermost Serra da Saudade Formation is an interval of up to 60\u00a0m\u2010thick of carbonate rocks disposed into two shallowing upward trends. Inner to outer ramp and high\u2010energy shoal deposits are described, in which laminated microbialites are the prevailing sedimentary facies. REE\u00a0+\u00a0Y data suggest contamination by iron (oxy)hydroxides that are dissociated from the riverine detritic flux. Sedimentary iron enrichment may be related to the settling of iron nanoparticles in coastal environments, diagenetic iron mobilization, or both. MREE enrichment is caused by microbial degradation of organic matter in the iron reduction zone during the anoxic early\u2010diagenetic stage. Chromium isotopes yielded negatively fractionated values (\u03b4\n                    <jats:sup>53<\/jats:sup>\n                    Cr\u00a0=\u00a0\u22120.69 to \u22120.27\u2030), probably resulting from biotic and abiotic reduction of dissolved Cr(VI) to light and less toxic Cr(III) within pores of microbial mats. The \u03b4\n                    <jats:sup>53<\/jats:sup>\n                    Cr data of the Ja\u00edba microbialite are thus a product of metabolic reactions in microbial mats and do not reflect seawater signal. The isotopic offset from seawater is feasible from molecular diffusion of Cr into pore water and reduction reactions occurring deep inside the mat, although the exact mechanism and consequences are not yet fully understood due to the poor preservation of metabolic reactions in the geological record. Our study suggests that Cr isotopes can be used to reconstruct Cr and other metals cycling within ancient microbial mats, and that caution should be taken when using past microbialites to infer seawater Cr records and redox state of the atmosphere and ocean.\n                  <\/jats:p>","DOI":"10.1111\/gbi.12426","type":"journal-article","created":{"date-parts":[[2020,12,21]],"date-time":"2020-12-21T23:42:50Z","timestamp":1608594170000},"page":"125-146","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Microbially induced chromium isotope fractionation and trace elements behavior in lower Cambrian microbialites from the Ja\u00edba Member, Bambu\u00ed Basin, Brazil"],"prefix":"10.1111","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8988-3783","authenticated-orcid":false,"given":"Gabriel J.","family":"Uhlein","sequence":"first","affiliation":[{"name":"Centro de Pesquisas Manoel Teixeira da Costa Instituto de Geoci\u00eancias Universidade Federal de Minas Gerais Belo Horizonte Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0335-3667","authenticated-orcid":false,"given":"Fabr\u00edcio A.","family":"Caxito","sequence":"additional","affiliation":[{"name":"Centro de Pesquisas Manoel Teixeira da Costa Instituto de Geoci\u00eancias Universidade Federal de Minas Gerais Belo Horizonte Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7708-9881","authenticated-orcid":false,"given":"Robert","family":"Frei","sequence":"additional","affiliation":[{"name":"Department of Geoscience and Natural Resource Management University of Copenhagen Copenhagen Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexandre","family":"Uhlein","sequence":"additional","affiliation":[{"name":"Centro de Pesquisas Manoel Teixeira da Costa Instituto de Geoci\u00eancias Universidade Federal de Minas Gerais Belo Horizonte Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7584-0600","authenticated-orcid":false,"given":"Alcides N.","family":"Sial","sequence":"additional","affiliation":[{"name":"Departamento de Geologia NEG\u2010LABISE Universidade Federal de Pernambuco Recife Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7954-5059","authenticated-orcid":false,"given":"Elton L.","family":"Dantas","sequence":"additional","affiliation":[{"name":"Instituto de Geoci\u00eancias Universidade de Bras\u00edlia Bras\u00edlia Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,12,21]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0016-7037(98)00279-8"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1098\/rsta.1988.0048"},{"key":"e_1_2_10_4_1","first-page":"36","article-title":"Reduction of hexavalent chromium by Escherichia coli ATCC 33456 in batch and continuous cultures","volume":"38","author":"Bae W. 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