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The stomatal uptake of O\n                    <jats:sub>3<\/jats:sub>\n                    is a substantial sink of O\n                    <jats:sub>3<\/jats:sub>\n                    , but it can create oxidative stress within plants, reducing photosynthesis and crop yields. In seasonally dry climates, stomatal regulation causes temporal decoupling between stomatal conductance and atmospheric O\n                    <jats:sub>3<\/jats:sub>\n                    concentrations protecting vegetation from high stomatal uptake of O\n                    <jats:sub>3<\/jats:sub>\n                    during peak ambient concentrations in the afternoon, but less is known about this temporal decoupling over agricultural fields in continental humid climates. Here, we investigate how maize (\n                    <jats:styled-content style=\"fixed-case\">\n                      <jats:italic>Zea mays<\/jats:italic>\n                    <\/jats:styled-content>\n                    L.) ecophysiology impacts O\n                    <jats:sub>3<\/jats:sub>\n                    dry deposition and diurnal O\n                    <jats:sub>3<\/jats:sub>\n                    exposure\u2010dose dynamics at an agricultural field in the central Corn Belt of the United States. We measured the field\u2010scale eddy covariance flux of O\n                    <jats:sub>3<\/jats:sub>\n                    using a UV\u2010absorption based instrument, the NASA Rapid Ozone Experiment (ROZE). The stomatal component of total O\n                    <jats:sub>3<\/jats:sub>\n                    flux was estimated with an inversion of the Penman\u2013Monteith equation using observed latent heat flux and a model of stomatal conductance using gross primary productivity. We found that maize stomatal conductance remained high as vapor pressure deficit increased during the afternoon. The diurnal synchrony between O\n                    <jats:sub>3<\/jats:sub>\n                    concentrations and stomatal conductance resulted in high stomatal uptake of O\n                    <jats:sub>3<\/jats:sub>\n                    during peak O\n                    <jats:sub>3<\/jats:sub>\n                    concentrations. The monthly mean stomatal flux reached &gt;\u200970% of the total O\n                    <jats:sub>3<\/jats:sub>\n                    flux to the land surface during high leaf area index. Furthermore, the total deposition velocity of O\n                    <jats:sub>3<\/jats:sub>\n                    was tightly coupled with stomatal conductance. Our findings suggest that maize ecophysiology in our field in the Corn Belt of the United States couples high O\n                    <jats:sub>3<\/jats:sub>\n                    stomatal uptake with high O\n                    <jats:sub>3<\/jats:sub>\n                    exposure. Furthermore, our study demonstrates the first use of NASA ROZE to measure growing season O\n                    <jats:sub>3<\/jats:sub>\n                    flux over an agricultural field, and NASA ROZE will be crucial for expanding O\n                    <jats:sub>3<\/jats:sub>\n                    flux measurements necessary for studying O\n                    <jats:sub>3<\/jats:sub>\n                    dry deposition and field\u2010scale phytotoxic dose across other fields.\n                  <\/jats:p>","DOI":"10.1111\/gcb.70952","type":"journal-article","created":{"date-parts":[[2026,6,5]],"date-time":"2026-06-05T14:51:36Z","timestamp":1780671096000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Maize Crops Face High Stomatal Uptake During High Exposure to Ozone in an Agroecosystem in the United States Corn Belt"],"prefix":"10.1111","volume":"32","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2078-7942","authenticated-orcid":false,"given":"Anam M.","family":"Khan","sequence":"first","affiliation":[{"name":"Department of Forest and Wildlife Ecology University of Wisconsin\u2010Madison  Madison Wisconsin USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Reem","family":"Hannun","sequence":"additional","affiliation":[{"name":"Atmospheric Science Branch NASA Ames Research Center  Mountain View California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3199-8999","authenticated-orcid":false,"given":"Elizabeth A.","family":"Ainsworth","sequence":"additional","affiliation":[{"name":"Department of Crop Sciences and Plant Biology University of Illinois Urbana\u2010Champaign  Chicago Illinois USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lun","family":"Gao","sequence":"additional","affiliation":[{"name":"Department of Natural Resources and Environmental Sciences, College of Agricultural, Consumers, and Environmental Sciences University of Illinois Urbana\u2010Champaign  Chicago Illinois USA"},{"name":"Agroecosystem Sustainability Center, Institute for Sustainability, Energy, and Environment University of Illinois Urbana\u2010Champaign  Chicago Illinois USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2397-425X","authenticated-orcid":false,"given":"Carl J.","family":"Bernacchi","sequence":"additional","affiliation":[{"name":"Global Change and Photosynthesis Research Unit USDA ARS  Chicago Illinois USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaiyu","family":"Guan","sequence":"additional","affiliation":[{"name":"Department of Natural Resources and Environmental Sciences, College 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