{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T16:03:20Z","timestamp":1787069000332,"version":"build-2736575974"},"reference-count":10,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2007,12,10]],"date-time":"2007-12-10T00:00:00Z","timestamp":1197244800000},"content-version":"vor","delay-in-days":39,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Journal of Forensic Sciences"],"published-print":{"date-parts":[[2007,11]]},"abstract":"<jats:p>\n                    <jats:bold>Abstract:\u2002<\/jats:bold>\n                    Blood samples of two cases were analyzed preliminarily by a classical spectrophotometric method (VIS) and by an automated headspace gas chromatographic method with nitrogen\u2010phosphorus detector (HS\u2010GC\/NPD). In the former, hydrogen cyanide (HCN) was quantitatively determined by measuring the absorbance of chromophores forming as a result of interaction with chloramine T. In the automated HS\u2010GC\/NPD method, blood was placed in a headspace vial, internal standard (acetonitrile) and acetic acid were then added. This resulted in cyanide being liberated as HCN. The spectrophotometric (VIS) and HS\u2010GC\/NPD methods were validated on postmortem blood samples fortified with potassium cyanide in the ranges 0.5\u201310 and 0.05\u20135\u2003\u03bcg\/mL, respectively. Detection limits were 0.2\u2003\u03bcg\/mL for VIS and 0.05\u2003\u03bcg\/mL for HS\u2010GC\/NPD. This work shows that results obtained by means of the two procedures were insignificantly different and that they compared favorably. They are suitable for rapid diagnosis of cyanide in postmortem cases.\n                  <\/jats:p>","DOI":"10.1111\/j.1556-4029.2007.00570.x","type":"journal-article","created":{"date-parts":[[2010,9,22]],"date-time":"2010-09-22T05:51:45Z","timestamp":1285134705000},"page":"1401-1404","source":"Crossref","is-referenced-by-count":27,"title":["Blood Cyanide Determination in Two Cases of Fatal Intoxication: Comparison Between Headspace Gas Chromatography and a Spectrophotometric Method\n                    <sup>*<\/sup>"],"prefix":"10.1111","volume":"52","author":[{"given":"Veniero","family":"Gambaro","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sebastiano","family":"Arnoldi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eleonora","family":"Casagni","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lucia","family":"Dell\u2019Acqua","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chiara","family":"Pecoraro","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rino","family":"Froldi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2007,12,10]]},"reference":[{"key":"e_1_2_5_2_2","volume-title":"Casarett and Doull's toxicology: The basic science of poisons","author":"Admur MO","year":"1991"},{"key":"e_1_2_5_3_2","first-page":"221","volume-title":"Disposition of toxic drugs and chemicals in man","author":"Baselt RC","year":"2000"},{"key":"e_1_2_5_4_2","first-page":"233","volume-title":"Methods of forensic science","author":"Guatelli MA","year":"1964"},{"key":"e_1_2_5_5_2","volume-title":"Principles of forensic toxicology","author":"Levine B","year":"2003"},{"key":"e_1_2_5_6_2","doi-asserted-by":"publisher","DOI":"10.1093\/jat\/9.6.251"},{"key":"e_1_2_5_7_2","doi-asserted-by":"publisher","DOI":"10.1093\/jat\/19.1.31"},{"key":"e_1_2_5_8_2","doi-asserted-by":"publisher","DOI":"10.1520\/JFS15165J"},{"key":"e_1_2_5_9_2","doi-asserted-by":"publisher","DOI":"10.1093\/jat\/7.5.213"},{"key":"e_1_2_5_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1570-0232(02)00067-3"},{"key":"e_1_2_5_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac60004a017"}],"container-title":["Journal of Forensic Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1111%2Fj.1556-4029.2007.00570.x","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1111\/j.1556-4029.2007.00570.x","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,15]],"date-time":"2023-10-15T01:29:31Z","timestamp":1697333371000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1111\/j.1556-4029.2007.00570.x"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2007,11]]},"references-count":10,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2007,11]]}},"alternative-id":["10.1111\/j.1556-4029.2007.00570.x"],"URL":"https:\/\/doi.org\/10.1111\/j.1556-4029.2007.00570.x","archive":["Portico"],"relation":{},"ISSN":["0022-1198","1556-4029"],"issn-type":[{"value":"0022-1198","type":"print"},{"value":"1556-4029","type":"electronic"}],"subject":[],"published":{"date-parts":[[2007,11]]}}}