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This preregistered study examined changes in time spent alone from 7th to 12th grade, as well as relationship and personality predictors of time spent alone in adolescence and loneliness in early adulthood, using data from a longitudinal study of 674 Mexican\u2010origin youth in the United States, a rapidly growing yet understudied demographic. Time spent alone showed linear increases from 7th to 12th grade, with greater increases in time spent alone in high school for youth who spent a high proportion of time alone at the start of high school (9th grade). Greater time spent alone in 9th grade was significantly predicted by gender, lower peer relationship quality, parent\u2013child support, parental warmth, higher parent\u2013child conflict, parental hostility, and youth neuroticism. However, there were no significant predictors of change in time spent alone throughout the course of high school (from 9th to 12th grade). 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