{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T03:19:44Z","timestamp":1792639184574,"version":"4.5.0"},"reference-count":67,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2025,8,26]],"date-time":"2025-08-26T00:00:00Z","timestamp":1756166400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["nyaspubs.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Ann NY Acad Sci"],"published-print":{"date-parts":[[2025,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    We investigated direct calcination of four precursors: calcium oxalate (CaC\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    ; denoted as CaO\u20101), calcium carbonate (CaCO\n                    <jats:sub>3<\/jats:sub>\n                    ; CaO\u20102), calcium\n                    <jats:sc>d<\/jats:sc>\n                    \u2010gluconate monohydrate (C\n                    <jats:sub>12<\/jats:sub>\n                    H\n                    <jats:sub>22<\/jats:sub>\n                    CaO\n                    <jats:sub>14<\/jats:sub>\n                    \u00b7H\n                    <jats:sub>2<\/jats:sub>\n                    O; CaO\u20103), and a commercial calcium carbonate (CaO\u20104). The effects of precursor selection on CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption performance were systematically compared. CaO\u20101 exhibited superior initial CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption capacity (0.63\u00a0g\/g) due to hierarchical porosity, but suffered a 38% capacity loss after 10 cycles from sintering. Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    doping (CaO\u2013Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    , 95\/5) enhanced capacity and kinetics (0.65\u00a0g\/g and 0.23\u00a0g\/g\u00b7min\n                    <jats:sup>\u22121<\/jats:sup>\n                    , respectively), showing 3% and 43.75% improvements over CaO\u20101, respectively, though a degradation of 33.8% occurred after 20 cycles. MgO doping (CaO\u2013MgO, 85\/15) achieved exceptional cyclic stability, retaining 93% capacity over 10 cycles (55% improvement vs. CaO\u20101) via inherent sintering resistance. Characterization experiments confirmed their structural evolution: Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    stabilized pore networks, while MgO preserved framework integrity. The results demonstrate that precursor engineering and dopant selection critically influence adsorption kinetics versus cyclic stability trade\u2010offs. Optimal CaO\u2013Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    (95\/5) and CaO\u2013MgO (85\/15) compositions propose a kinetics\u2013stability decoupling strategy. This dual\u2010dopant approach addresses calcium looping challenges by balancing rapid CO\n                    <jats:sub>2<\/jats:sub>\n                    capture with structural durability, providing insights for cost\u2010effective adsorbent optimization.\n                  <\/jats:p>","DOI":"10.1111\/nyas.70026","type":"journal-article","created":{"date-parts":[[2025,8,27]],"date-time":"2025-08-27T04:55:10Z","timestamp":1756270510000},"page":"388-400","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":61,"title":["Al\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    \/MgO\u2010doped, CaO\u2010based adsorbents for CO\n                    <sub>2<\/sub>\n                    capture: A performance study"],"prefix":"10.1111","volume":"1552","author":[{"given":"Chengzhuang","family":"Zhang","sequence":"first","affiliation":[{"name":"Key Laboratory of Fluid and Power Machinery, Ministry of Education, School of Energy and Power Engineering Xihua University Chengdu China"},{"name":"School of Automobile and Transportation Xihua University Chengdu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6843-3791","authenticated-orcid":false,"given":"Jia","family":"Fang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Fluid and Power Machinery, Ministry of Education, School of Energy and Power Engineering Xihua University Chengdu China"},{"name":"School of Automobile and Transportation Xihua University Chengdu China"},{"name":"Engineering Research Center of Intelligent Space Ground Integration Vehicle and Control, Ministry of Education Xihua University  Chengdu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xilong","family":"Xu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Fluid and Power Machinery, Ministry of Education, School of Energy and Power Engineering Xihua University Chengdu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Mathematics University of North Georgia  Dahlonega Georgia USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqiang","family":"Han","sequence":"additional","affiliation":[{"name":"School of Automobile and Transportation Xihua University Chengdu China"},{"name":"Engineering Research Center of Intelligent Space Ground Integration Vehicle and Control, Ministry of Education Xihua University  Chengdu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianxiong","family":"Liao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Fluid and Power Machinery, Ministry of Education, School of Energy and Power Engineering Xihua University Chengdu China"},{"name":"School of Automobile and Transportation Xihua University Chengdu China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,8,26]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2022.112123"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seta.2023.103365"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules30051161"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.129110"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/er.5206"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2020.114874"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2019.117738"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtsust.2023.100491"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-04794-5"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11051-017-4092-3"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.energy.2018.04.180"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00025F"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2018.12.061"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.susmat.2023.e00778"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jiec.2023.12.048"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2022.135579"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jare.2019.10.008"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.9b01058"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie051325x"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2013.03.078"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.7b02751"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.7b05034"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1166\/jctn.2013.2735"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.130864"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2016.07.145"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.129479"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2018.05.014"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/ente.201800300"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2021.101747"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enconman.2022.116461"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201400862"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.159237"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.1c02428"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/ghg.2213"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3DT03322H"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202312583"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.3390\/en17081918"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2022.112334"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joei.2023.101407"},{"key":"e_1_2_9_41_1","doi-asserted-by":"crossref","unstructured":"Fang 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