{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T10:18:17Z","timestamp":1789553897753,"version":"build-2803163510"},"reference-count":62,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2025,9,16]],"date-time":"2025-09-16T00:00:00Z","timestamp":1757980800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["nyaspubs.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Ann NY Acad Sci"],"published-print":{"date-parts":[[2025,11]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Deep coal seams offer considerable potential for simultaneous carbon sequestration and methane extraction. When injected into reservoirs, such as coal seams, CO\n                    <jats:sub>2<\/jats:sub>\n                    transitions into a supercritical state (supercritical CO\n                    <jats:sub>2<\/jats:sub>\n                    or Sc\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    ), altering the internal structure and mechanical properties of coal. This study investigates the effects of the Sc\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    soaking duration on coal strength via triaxial compression tests. The strength and elastic modulus of coal both decreased with increasing Sc\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    soaking time, and the most prominent reduction occurs within the initial 1 day. A constitutive model is developed to characterize the mechanical properties of coal. This model simultaneously incorporates the degradation of the elastic modulus of coal owing to Sc\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    exposure and the failure evolution based on a Weibull statistical distribution of microelement strength. This model successfully reproduces the stress\u2013strain responses for different treatment durations, exhibiting high consistency with the experimental data. Sc\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    damages the pore structure of coal through coupled physicochemical interactions, progressively deteriorating the macroscopic mechanical properties of coal. These findings provide valuable insights into the evolution of the mechanical properties of coal during carbon sequestration and aid the assessment of the long\u2010term stability of CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010sequestered coal seams.\n                  <\/jats:p>","DOI":"10.1111\/nyas.70091","type":"journal-article","created":{"date-parts":[[2025,9,16]],"date-time":"2025-09-16T18:05:08Z","timestamp":1758045908000},"page":"477-490","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Mechanical Properties and Damage Constitutive Model of Coal Under Supercritical CO\n                    <sub>2<\/sub>\n                    Conditions"],"prefix":"10.1111","volume":"1553","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-0816-6804","authenticated-orcid":false,"given":"Yang","family":"Chen","sequence":"first","affiliation":[{"name":"School of Civil Engineering and Architecture Anhui University of Science and Technology  Huainan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Civil Engineering and Architecture Anhui University of Science and Technology  Huainan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenyu","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Digital and Intelligent Technology For Unmanned Coal Mining Anhui University of Science and Technology  Huainan China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,16]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.26804\/ager.2019.02.10"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40948-019-00139-8"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.energy.2022.125473"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40948-019-00135-y"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.5b00058"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.26804\/ager.2019.03.08"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coal.2011.04.011"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coal.2005.09.002"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2014.08.035"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.petrol.2018.11.044"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coal.2018.09.009"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2024.174261"},{"issue":"6","key":"e_1_2_10_14_1","first-page":"2630","article-title":"Meso\u2010Statistical Damage Constitutive Model and Validation of Coal Under CO2\u2014Load Coupling","volume":"49","author":"Wang L.","year":"2024","journal-title":"Journal of China Coal Society"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2010.03.025"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmps.2012.06.012"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.3390\/en9060440"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijrmms.2018.04.033"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.energy.2023.129599"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.3c01442"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coal.2016.08.027"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2013.03.069"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jngse.2014.12.020"},{"issue":"12","key":"e_1_2_10_24_1","first-page":"4487","article-title":"Shear Hardening Characteristics and Constitutive Model of Coal Structural Plane After Supercritical CO2 Soaking","volume":"48","author":"Wei J.","year":"2023","journal-title":"Journal of China Coal Society"},{"key":"e_1_2_10_25_1","first-page":"1","article-title":"Fracture Structure and Dynamic Characteristics of Coal After Various Supercritical\u2010CO2 Soaking Times","author":"Jin K.","year":"2025","journal-title":"Annals of the New York Academy of Sciences"},{"issue":"8","key":"e_1_2_10_26_1","first-page":"2251","article-title":"Energy Evolution and Failure Characteristics of Impacted Coal After Varying Durations of Supercritical CO2 Immersion Corrosion","volume":"45","author":"Wang L.","year":"2024","journal-title":"Rock and Soil Mechanics"},{"issue":"6","key":"e_1_2_10_27_1","first-page":"2340","article-title":"Mechanical Damage Evolution Characteristics and Mechanism of Anthracite Treated With Supercritical CO2","volume":"47","author":"Xiao C.","year":"2022","journal-title":"Journal of China Coal Society"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ef0301349"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coal.2019.04.004"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1115\/1.3225775"},{"issue":"1","key":"e_1_2_10_31_1","first-page":"30","article-title":"New Study of Damage Variable and Constitutive Equation of Rock","volume":"22","author":"Zhang Q. S.","year":"2003","journal-title":"Chinese Journal of Rock Mechanics and Engineering"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2013.03.069"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.supflu.2015.11.010"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jngse.2018.11.010"},{"issue":"3","key":"e_1_2_10_35_1","first-page":"279","article-title":"The Quantitative Analysis of Distribution Regulation of CT Values of Rock Damage","volume":"17","author":"Yang G. S.","year":"1998","journal-title":"Chinese Journal of Rock Mechanics and Engineering"},{"key":"e_1_2_10_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/0029-5493(84)90169-9"},{"key":"e_1_2_10_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/0020-7683(82)90039-7"},{"issue":"12","key":"e_1_2_10_38_1","first-page":"226","article-title":"Statistical Damage Constitutive Model Forsilty Clay After Freeze\u2010Thaw Cycling","volume":"44","author":"Wang S. H.","year":"2016","journal-title":"Journal of Northwest A & F University (Natural Science)"},{"issue":"6","key":"e_1_2_10_39_1","first-page":"1652","article-title":"Study of Modified Statistical Damage Softening Constitutive Model for Rock Considering Residual Strength","volume":"34","author":"Cao R. L.","year":"2013","journal-title":"Rock and Soil Mechanics"},{"issue":"1","key":"e_1_2_10_40_1","first-page":"38","article-title":"Statistical Damage Constitutive Model for Rock Based on SMP Criterion","volume":"31","author":"Feng Q. B.","year":"2021","journal-title":"Journal of Heilongjiang University of Science and Technology"},{"key":"e_1_2_10_41_1","volume-title":"Study on Macro Mechanical Properties and Micro Structure of Coal Under Supercritical CO2","author":"He L. G.","year":"2022"},{"issue":"12","key":"e_1_2_10_42_1","first-page":"2932","article-title":"Study on Mechanical Properties and Constitutive Relation of Brittle Coal Based on Triaxial Compression","volume":"42","author":"Liu H. T.","year":"2023","journal-title":"Chinese Journal of Rock Mechanics and Engineering"},{"key":"e_1_2_10_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2011.11.025"},{"key":"e_1_2_10_44_1","volume-title":"Structural Response of Bituminous Coal Under Supercritical CO2 and Its Influence Mechanism on Mechanical and Permeability Properties","author":"Su E. L.","year":"2022"},{"key":"e_1_2_10_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie9000162"},{"key":"e_1_2_10_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coal.2015.01.005"},{"key":"e_1_2_10_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.egypro.2011.02.228"},{"key":"e_1_2_10_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1750-5836(07)00120-X"},{"key":"e_1_2_10_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coal.2003.08.001"},{"key":"e_1_2_10_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/ef060040"},{"key":"e_1_2_10_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jngse.2017.02.031"},{"key":"e_1_2_10_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2019.116077"},{"key":"e_1_2_10_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2019.01.008"},{"key":"e_1_2_10_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.6b03225"},{"key":"e_1_2_10_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coal.2019.02.004"},{"key":"e_1_2_10_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/ef900084b"},{"key":"e_1_2_10_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2021.120639"},{"key":"e_1_2_10_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2025.135185"},{"key":"e_1_2_10_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2018.01.115"},{"key":"e_1_2_10_60_1","article-title":"Effect of Supercritical\u2010CO2 Interaction Time on the Alterations in Coal Pore Structure","volume":"76","author":"Sampath K. H. S. M.","year":"2020","journal-title":"Gas Science and Engineering"},{"key":"e_1_2_10_61_1","doi-asserted-by":"publisher","DOI":"10.1098\/rsta.1921.0006"},{"key":"e_1_2_10_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coal.2006.04.006"},{"key":"e_1_2_10_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2016.12.011"}],"container-title":["Annals of the New York Academy of Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/nyaspubs.onlinelibrary.wiley.com\/doi\/pdf\/10.1111\/nyas.70091","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T08:49:42Z","timestamp":1764060582000},"score":1,"resource":{"primary":{"URL":"https:\/\/nyaspubs.onlinelibrary.wiley.com\/doi\/10.1111\/nyas.70091"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,16]]},"references-count":62,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2025,11]]}},"alternative-id":["10.1111\/nyas.70091"],"URL":"https:\/\/doi.org\/10.1111\/nyas.70091","archive":["Portico"],"relation":{},"ISSN":["0077-8923","1749-6632"],"issn-type":[{"value":"0077-8923","type":"print"},{"value":"1749-6632","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,16]]},"assertion":[{"value":"2025-05-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-08-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-16","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}