{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T14:00:40Z","timestamp":1790431240100,"version":"4.1.0"},"reference-count":48,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T00:00:00Z","timestamp":1789516800000},"content-version":"vor","delay-in-days":15,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T00:00:00Z","timestamp":1788220800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["nyaspubs.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Ann NY Acad Sci"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The rising concentration of greenhouse gases causes severe global warming, creating an urgent need for efficient and low\u2010cost carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) adsorption technologies. Corn stover is an abundant agricultural waste that is often underutilized, leading to resource waste and environmental pollution. To develop value\u2010added utilization of this material, corn stover\u2212derived activated carbon is prepared via urea predoping and controlled potassium hydroxide (KOH) etching, while the effects of pyrolysis temperature, urea doping ratio, KOH dosage, and activation temperature are investigated. Under pure CO\n                    <jats:sub>2<\/jats:sub>\n                    at 25\u00b0C, the optimal adsorbent exhibits an equilibrium CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption capacity of 3.57 mmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Under pure CO\n                    <jats:sub>2<\/jats:sub>\n                    at 0\u00b0C, the equilibrium capacity increases to 5.91 mmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , indicating that lower temperature favors CO\n                    <jats:sub>2<\/jats:sub>\n                    physical adsorption. Under a typical flue gas composition of 20% CO\n                    <jats:sub>2<\/jats:sub>\n                    \/80% N\n                    <jats:sub>2<\/jats:sub>\n                    at 25\u00b0C, the adsorbent achieves a CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake of 1.78 mmol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 50\u00a0min. The adsorbent exhibits an ideal adsorbed solution theory CO\n                    <jats:sub>2<\/jats:sub>\n                    \/N\n                    <jats:sub>2<\/jats:sub>\n                    selectivity of 30.92. The isosteric heat of adsorption ranges from 28.42 to 23.75 kJ\u00b7mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    . These values suggest predominantly physical adsorption on heterogeneous sites associated with nitrogen functionalities and structural defects. This study offers insights into the design of biomass\u2010derived CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorbents based on corn stover.\n                  <\/jats:p>","DOI":"10.1111\/nyas.70406","type":"journal-article","created":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T13:26:55Z","timestamp":1789565215000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Urea\u2010Predoped, KOH\u2010Activated, Corn Stover\u2013Derived Carbon for CO\n                    <sub>2<\/sub>\n                    Adsorption"],"prefix":"10.1111","volume":"1563","author":[{"given":"Yize","family":"Dang","sequence":"first","affiliation":[{"name":"Key Laboratory of Fluid and Power Machinery, Ministry of Education Xihua University  Chengdu China"},{"name":"School of Automobile and Transportation Xihua University  Chengdu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zilong","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Automobile and Transportation Xihua University  Chengdu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengzhuang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Fluid and Power Machinery, Ministry of Education Xihua University  Chengdu China"},{"name":"School of Automobile and Transportation Xihua University  Chengdu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqiang","family":"Han","sequence":"additional","affiliation":[{"name":"Key Laboratory of Fluid and Power Machinery, Ministry of Education Xihua University  Chengdu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zinong","family":"Zuo","sequence":"additional","affiliation":[{"name":"Key Laboratory of Fluid and Power Machinery, Ministry of Education Xihua University  Chengdu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kun","family":"Liang","sequence":"additional","affiliation":[{"name":"Department of Engineering and Design University of Sussex  Brighton UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Fang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Fluid and Power Machinery, Ministry of Education Xihua University  Chengdu China"},{"name":"Sichuan Yilan Zhichuang Technology Co., Ltd.  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