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Micro\u2010proton\u2010induced X\u2010ray emission and laser ablation inductively coupled mass spectrometry analyses indicated hot spots of<jats:styled-content style=\"fixed-case\">C<\/jats:styled-content>d concentrations in the vicinity of vascular bundles in response to<jats:styled-content style=\"fixed-case\">C<\/jats:styled-content>d treatment, essentially bound to<jats:styled-content style=\"fixed-case\">S<\/jats:styled-content>\u2010containing compounds as revealed by extended X\u2010ray absorption fine structure and non\u2010protein thiol compounds analyses. A preferential accumulation of<jats:styled-content style=\"fixed-case\">Z<\/jats:styled-content>n occurred in vascular bundle and spongy mesophyll in response to<jats:styled-content style=\"fixed-case\">Z<\/jats:styled-content>n treatment, and was mainly bound to<jats:styled-content style=\"fixed-case\">O<\/jats:styled-content>\/<jats:styled-content style=\"fixed-case\">N<\/jats:styled-content>\u2010ligands. 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