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Conversion to a photoactive species during irradiation is consistent with the acceleration of the decomposition rate during the early stages and with the apparent inverse dependence of the decomposition rate on the initial concentration of RuCl<jats:sub>6<\/jats:sub><jats:sup>2\u2212<\/jats:sup>. The displacement of Cl<jats:sup>\u2212<\/jats:sup> by CHCl<jats:sub>3<\/jats:sub> in the coordination sphere to create the photoactive species is consistent with the retardation of photodecomposition by both Cl<jats:sup>\u2212<\/jats:sup> and H<jats:sub>2<\/jats:sub>O. The much smaller photodecomposition rate in CDCl<jats:sub>3<\/jats:sub> suggests that C\u2013H bond dissociation occurs during the primary photochemical event, which is also consistent with the presence of a CHCl<jats:sub>3<\/jats:sub> molecule in the first coordination sphere.<\/jats:p>","DOI":"10.1111\/php.12005","type":"journal-article","created":{"date-parts":[[2012,10,10]],"date-time":"2012-10-10T23:27:27Z","timestamp":1349911647000},"page":"274-279","source":"Crossref","is-referenced-by-count":9,"title":["Photocatalysis of Chloroform Decomposition by the Hexachlororuthenate(<scp>IV<\/scp>) Ion"],"prefix":"10.1111","volume":"89","author":[{"given":"Alissa M.","family":"Chan","sequence":"first","affiliation":[{"name":"Department of Chemistry Santa Clara University Santa Clara CA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Laura A.","family":"Pe\u00f1a","sequence":"additional","affiliation":[{"name":"Department of Chemistry Santa Clara University Santa Clara CA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rosa E.","family":"Segura","sequence":"additional","affiliation":[{"name":"Department of Chemistry Santa Clara University Santa Clara CA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ramya","family":"Auroprem","sequence":"additional","affiliation":[{"name":"Department of Chemistry Santa Clara University Santa Clara CA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Brent M.","family":"Harvey","sequence":"additional","affiliation":[{"name":"Department of Chemistry Santa Clara University Santa Clara CA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Caroline M.","family":"Brooke","sequence":"additional","affiliation":[{"name":"Department of Chemistry Santa Clara University Santa Clara CA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Patrick E.","family":"Hoggard","sequence":"additional","affiliation":[{"name":"Department of Chemistry Santa Clara University Santa Clara CA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2012,11,8]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00706-009-0175-x"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2010.01.032"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.2009.00669.x"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2010.05.005"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/b814585g"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp960572z"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/0146-5724(80)90224-1"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/0047-2670(80)80006-2"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/kin.550190405"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/1010-6030(87)80001-1"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470523674.ch19"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(00)00384-5"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00894-011-0988-5"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2006.12.079"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(02)01378-6"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/b609999h"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1080\/00958970802702254"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic800684v"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1998.tb02480.x"},{"key":"e_1_2_6_21_1","unstructured":"Lindsey J. 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