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The reaction is proposed to proceed in two stages, the first stage yielding <jats:styled-content style=\"fixed-case\">CC<\/jats:styled-content>l<jats:sub>4<\/jats:sub> and <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/php12336-math-0002.gif\" xlink:title=\"urn:x-wiley:00318655:media:php12336:php12336-math-0002\"\/> as products, the second consisting of a chain reaction resulting from the <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/php12336-math-0003.gif\" xlink:title=\"urn:x-wiley:00318655:media:php12336:php12336-math-0003\"\/>\u2010catalyzed photodissociation of <jats:styled-content style=\"fixed-case\">CC<\/jats:styled-content>l<jats:sub>4<\/jats:sub>, yielding phosgene with <jats:styled-content style=\"fixed-case\">CC<\/jats:styled-content>l<jats:sub>3<\/jats:sub> radicals as chain carriers. Photodecomposition is retarded by added Cl<jats:sup>\u2212<\/jats:sup>, <jats:styled-content style=\"fixed-case\">CH<\/jats:styled-content><jats:sub>3<\/jats:sub><jats:styled-content style=\"fixed-case\">CN<\/jats:styled-content>, C<jats:sub>6<\/jats:sub>H<jats:sub>12<\/jats:sub> or C<jats:sub>2<\/jats:sub>H<jats:sub>5<\/jats:sub><jats:styled-content style=\"fixed-case\">OH<\/jats:styled-content>, which is ascribed to the displacement of <jats:styled-content style=\"fixed-case\">CHC<\/jats:styled-content>l<jats:sub>3<\/jats:sub> molecules from the vicinity of the copper by attraction to the polystyrene matrix or to the alkylammonium cation sites.<\/jats:p>","DOI":"10.1111\/php.12336","type":"journal-article","created":{"date-parts":[[2014,8,25]],"date-time":"2014-08-25T07:06:17Z","timestamp":1408950377000},"page":"1234-1242","source":"Crossref","is-referenced-by-count":4,"title":["Photocatalysis of Chloroform Decomposition by Tetrachlorocuprate (<scp>II<\/scp>) on Dowex 2\u2010X8"],"prefix":"10.1111","volume":"90","author":[{"given":"Brent M.","family":"Harvey","sequence":"first","affiliation":[{"name":"Department of Chemistry Santa Clara University Santa Clara CA USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Patrick E.","family":"Hoggard","sequence":"additional","affiliation":[{"name":"Department of Chemistry Santa Clara University Santa Clara CA USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2014,9,25]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic800684v"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3pp50094b"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1080\/00102209208947177"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp044218"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/0301-0104(94)80012-X"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1139\/v66-211"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cp55348e"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100042a012"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/0146-5724(80)90224-1"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/0047-2670(80)80006-2"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/kin.550190405"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp960572z"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/1010-6030(87)80001-1"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp003877t"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(00)00384-5"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00352a014"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1841092"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19850970107"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.2174\/2211544711302020001"},{"key":"e_1_2_6_21_1","unstructured":"Bio\u2010Rad Laboratories.AG 1 AG MP\u20101 and AG 2 Strong Anion Exchange Resin Instruction Manual (LIT212 Rev C)."},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1998.tb02480.x"},{"key":"e_1_2_6_23_1","unstructured":"Lindsey J. 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