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The photophysical behavior of complex 3 was compared to that of the Zn derivative (tetrakis\u2010[(thiophineethoxy) phthalocyaninato] zinc(<jats:styled-content style=\"fixed-case\">II<\/jats:styled-content>) (complex 2)). The compounds were interacted with gold\u2010speckled silica (<jats:styled-content style=\"fixed-case\">GSS<\/jats:styled-content>) nanoparticles via Au\u2013S self assembly to afford the conjugates (2\u2013<jats:styled-content style=\"fixed-case\">GSS<\/jats:styled-content> and 3\u2013<jats:styled-content style=\"fixed-case\">GSS<\/jats:styled-content>). The photophysicochemical behavior of the compounds and their conjugates were assessed. The conjugates afforded a decrease in fluorescence quantum yields and lifetimes with improved triplet and singlet oxygen quantum yields in comparison with complexes 2 and 3 alone. The complexes and their conjugates could serve as good candidates for photodynamic therapy.<\/jats:p>","DOI":"10.1111\/php.12879","type":"journal-article","created":{"date-parts":[[2017,12,24]],"date-time":"2017-12-24T09:50:33Z","timestamp":1514109033000},"page":"521-531","update-policy":"http:\/\/dx.doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Improved Photophysical and Photochemical Properties of Thiopheneethoxy Substituted Metallophthalocyanines on Immobilization onto Gold\u2010speckled Silica Nanoparticles"],"prefix":"10.1111","volume":"94","author":[{"given":"Edith","family":"Dube","sequence":"first","affiliation":[{"name":"Department of Chemistry Center for Nanotechnology Innovation Rhodes University Grahamstown South Africa"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"David O.","family":"Oluwole","sequence":"additional","affiliation":[{"name":"Department of Chemistry Center for Nanotechnology Innovation Rhodes University Grahamstown South Africa"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tebello","family":"Nyokong","sequence":"additional","affiliation":[{"name":"Department of Chemistry Center for Nanotechnology Innovation Rhodes University Grahamstown South Africa"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,3,25]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules21030342"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/B602830F"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0343095"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0nr00096e"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0jm00554a"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm902239a"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462424"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc03310c"},{"key":"e_1_2_6_10_1","first-page":"3","volume-title":"Topics in Current Chemistry","author":"Rampazzo E.","year":"2016"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0jm00354a"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm801020s"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1201\/9781482296952"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201301771"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja047649e"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules22071093"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2005.03.024"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/1011-1344(91)80006-4"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jlumin.2017.05.071"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm0492336"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt32698e"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2013.01.037"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochem.2013.01.009"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1364\/OL.32.000856"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1186\/1556-276X-7-386"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ed076p1260"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100341a013"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/B315319C"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1012369120376"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-1409(199803\/04)2:2<145::AID-JPP60>3.0.CO;2-2"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1142\/9789814307246_0006"},{"key":"e_1_2_6_32_1","doi-asserted-by":"crossref","first-page":"43","DOI":"10.1016\/B978-0-08-092390-1.50008-4","volume-title":"Handbook of Porphyrin and Related Macrocycles","author":"Mack J.","year":"2003"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT00304K"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1142\/S1088424610001726"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2006.05.011"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-220103-5.50008-8"},{"key":"e_1_2_6_37_1","first-page":"134","volume-title":"Phthalocyanines: Properties and Applications","author":"Stillman M. 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