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Measurements of electronic absorption, circular dichroism and infrared absorption spectra revealed that the zinc complex of a Chl\u2010<jats:italic>a<\/jats:italic> derivative bearing a (<jats:italic>p<\/jats:italic>\u2010ethynyl)benzyl alcoholic moiety at the C20\u2010position gave its <jats:italic>J<\/jats:italic>\u2010aggregates in an aqueous micellar solution through the hydrogen and coordination bonding. These results exhibited the potential of Chl\u2010<jats:italic>a<\/jats:italic> derivatives bearing a hydroxyl group in the C20 substituents as the model compounds for chlorosomal light\u2010harvesting antennas.<\/jats:p>","DOI":"10.1111\/php.13655","type":"journal-article","created":{"date-parts":[[2022,5,23]],"date-time":"2022-05-23T07:23:58Z","timestamp":1653290638000},"page":"35-44","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Synthesis and <scp>Self\u2010Aggregation<\/scp> of Chlorophyll\u2010<i>a<\/i> Derivatives Possessing a Hydroxymethyl Group in the <scp>C20\u2010Substituent<\/scp> with Ethynylene and\/or Phenylene Linkers"],"prefix":"10.1111","volume":"99","author":[{"given":"Takeo","family":"Nakano","sequence":"first","affiliation":[{"name":"Graduate School of Life Sciences Ritsumeikan University  Kusatsu Shiga Japan"},{"name":"Research Center for Negative Emissions Technologies Kyushu University  744 Moto\u2010oka, Nishi\u2010ku Fukuoka Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yuki","family":"Hashimoto","sequence":"additional","affiliation":[{"name":"Graduate School of Life Sciences Ritsumeikan University  Kusatsu Shiga Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4797-0349","authenticated-orcid":false,"given":"Hitoshi","family":"Tamiaki","sequence":"additional","affiliation":[{"name":"Graduate School of Life Sciences Ritsumeikan University  Kusatsu Shiga Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2022,6,9]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201002307"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00581"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/0001-8686(77)80011-0"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1436076"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn201100m"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biomaterials.2020.120532"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201907754"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202105189"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3tc31243g"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20010518)7:10<2245::AID-CHEM2245>3.0.CO;2-W"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn9001165"},{"key":"e_1_2_7_13_1","first-page":"3471","article-title":"Bright solid\u2010state red\u2010emissive BODIPYs: Facile synthesis and their high\u2010contrast mechanochromic properties","volume":"7","author":"Duan C.","year":"2019","journal-title":"J. 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