{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,29]],"date-time":"2026-05-29T19:56:31Z","timestamp":1780084591990,"version":"3.54.0"},"reference-count":41,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2025,1,31]],"date-time":"2025-01-31T00:00:00Z","timestamp":1738281600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Photochem &amp;amp; Photobiology"],"published-print":{"date-parts":[[2025,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Photo\u2010biocatalyst coupled systems offer a promising approach for converting solar energy into valuable fuels. The bio\u2010integrated photocatalytic system sets a research benchmark by utilizing green energy for formic acid production, reducing CO\u2082 emissions, and enhancing selectivity through bio\u2010enzyme incorporation. This bio\u2010photocatalytic are promising solutions for environmental remediation and energy production. This research reports the synthesis and application of a novel metal\u2010free, nitrogen\u2010enriched graphene composite photocatalyst (N\n                    <jats:sub>en<\/jats:sub>\n                    GCTPP) for artificial photosynthesis. N\n                    <jats:sub>en<\/jats:sub>\n                    GCTPP was synthesized by covalently coupling tetraphenyl porphyrin tetracarboxylic acid (TPP) with N\u2010doped graphene via a polycondensation pathway. The photogenerated charge separation then facilitates the regeneration of enzymatically active coenzymes (NADH) for formic acid production catalyzed by formate dehydrogenase. The photocatalyst exhibited remarkable performance in photocatalytic regeneration of the coenzyme NADH from NAD\n                    <jats:sup>+<\/jats:sup>\n                    with a high yield of 41.80%, as well as photocatalytic production of formic acid (HCO\n                    <jats:sub>2<\/jats:sub>\n                    H) as a solar fuel from CO\n                    <jats:sub>2<\/jats:sub>\n                    with a yield of 99.12\u2009\u03bcM. This innovative artificial photosynthetic system demonstrates an affordable, highly efficient, and selective approach for converting carbon dioxide into valuable solar fuels and regenerating NADH, addressing environmental concerns and contributing to sustainable energy solutions.\n                  <\/jats:p>","DOI":"10.1111\/php.14069","type":"journal-article","created":{"date-parts":[[2025,1,31]],"date-time":"2025-01-31T06:01:42Z","timestamp":1738303302000},"page":"1480-1490","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Transforming\n                    <scp>\n                      CO\n                      <sub>2<\/sub>\n                    <\/scp>\n                    into formic acid by integrated solar\u2010driven catalyst\u2010enzyme coupled artificial photosynthetic system"],"prefix":"10.1111","volume":"101","author":[{"given":"Ankita","family":"Singh","sequence":"first","affiliation":[{"name":"Department of Chemistry and Environmental Science Madan Mohan Malaviya University of Technology  Gorakhpur India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5320-5259","authenticated-orcid":false,"given":"Rajesh K.","family":"Yadav","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Environmental Science Madan Mohan Malaviya University of Technology  Gorakhpur India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abhishek Kumar","family":"Gupta","sequence":"additional","affiliation":[{"name":"Department of Physics, School of Basic and Applied Sciences Harcourt Butler Technical University  Kanpur India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chandani","family":"Singh","sequence":"additional","affiliation":[{"name":"Department of Chemistry Central University South Bihar  Patna India"},{"name":"Korea Research Institute of Chemical Technology  Daejeon South Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kanchan","family":"Sharma","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Environmental Science Madan Mohan Malaviya University of Technology  Gorakhpur India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaifali","family":"Mishra","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Environmental Science Madan Mohan Malaviya University of Technology  Gorakhpur India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rehana","family":"Shahin","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Environmental Science Madan Mohan Malaviya University of Technology  Gorakhpur India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Atul P.","family":"Singh","sequence":"additional","affiliation":[{"name":"Department of Chemistry Central University South Bihar  Patna India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Krishna Kumar","family":"Yadav","sequence":"additional","affiliation":[{"name":"Faculty of Science and Technology Madhyanchal Professional University  Bhopal India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin\u2010Ook","family":"Baeg","sequence":"additional","affiliation":[{"name":"Korea Research Institute of Chemical Technology  Daejeon South Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,31]]},"reference":[{"key":"e_1_2_8_2_1","article-title":"Sun\u2010powered CO2 transformation: TBE\u2010Y photocatalyst's remarkable selectivity for solar\u2010induced HCOOH","volume":"548","author":"Sharma K","year":"2023","journal-title":"Photochemical conversion of solar energy. Mol Catal"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.3354\/cr013149"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pecs.2005.02.002"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2016.09.004"},{"key":"e_1_2_8_6_1","first-page":"37031","article-title":"Revealing the blueprint of photosynthesis","author":"Barber J","year":"1994","journal-title":"Nature"},{"key":"e_1_2_8_7_1","first-page":"126","article-title":"Photochemical conversion of solar energy. ChemSusChem Chem. & sustain","volume":"1","author":"Balzani V","year":"2008","journal-title":"Energy & Mater"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/B802262N"},{"key":"e_1_2_8_9_1","first-page":"199","article-title":"Enhancing Electrocatalytic Synthesis of Glycine with CuPb1ML Electrode Synthesized via Pb UPD","volume":"1","author":"Dimitra A","year":"2023","journal-title":"Commu Chem"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2017.03.037"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4GC00885E"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ta14442a"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/er.6638"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.diamond.2019.107648"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1111\/php.13793"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b03067"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b04150"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c02557"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules25163653"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2016.05.199"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1149\/1945-7111\/ab7099"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3009902"},{"key":"e_1_2_8_23_1","first-page":"193293","article-title":"Toward High\u2010Performance Hybrid Zn\u2010Based Batteries via Deeply Understanding Their Mechanism and Using Electrolyte Additive","volume":"29","author":"Hao J","year":"2016","journal-title":"Electrochim Acta"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-022-16931-8"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-018-35135-7"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TA01625A"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.10.077"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfb.2010.10.014"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CP02542C"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CY00936J"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1111\/php.13639"},{"key":"e_1_2_8_32_1","first-page":"1","article-title":"Evaluation of microstructure, mechanical properties and pitting corrosion in dissimilar of alternative low cost stainless steel grade 204Cu and 304 by GTA welding joint","volume":"22","author":"Bansod AV","year":"2019","journal-title":"Mater Res"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2020.128762"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TA06883D"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2015.10.002"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.1c03697"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CY00991E"},{"key":"e_1_2_8_38_1","first-page":"5438","article-title":"Acs Catal","volume":"7","author":"Huang W","year":"2017","journal-title":"J Am Chem Soc"},{"key":"e_1_2_8_39_1","doi-asserted-by":"crossref","unstructured":"HuJ KangZ LiF HuangX.Carbon N Y 2014 67 221\u2013229.","DOI":"10.1016\/j.carbon.2013.09.085"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201203207"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2018.06.162"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1111\/php.13735"}],"container-title":["Photochemistry and Photobiology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1111\/php.14069","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T09:44:58Z","timestamp":1763372698000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1111\/php.14069"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,31]]},"references-count":41,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2025,11]]}},"alternative-id":["10.1111\/php.14069"],"URL":"https:\/\/doi.org\/10.1111\/php.14069","archive":["Portico"],"relation":{},"ISSN":["0031-8655","1751-1097"],"issn-type":[{"value":"0031-8655","type":"print"},{"value":"1751-1097","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1,31]]},"assertion":[{"value":"2024-08-31","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-01-05","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-01-31","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}