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Oxygen-containing functional groups (predominately epoxies and hydroxyls) on the nongraphitized aliphatic carbons of the basal plane of GO formed highly polar regions that encompass graphitic regions slightly larger than the benzene ring. This facilitated size match\u2013based interactions between small apolar compounds and the isolated aromatic region of GO, resulting in high binding selectivity relative to larger apolar compounds. The interactions between the functional group(s) of polar aromatics and the epoxy\/hydroxyl groups around the isolated aromatic region of GO enhanced binding selectivity relative to similar-sized apolar aromatics. These findings provide opportunities for precision separations and molecular recognition enabled by size\/polarity match\u2013based selectivity.<\/jats:p>","DOI":"10.1126\/sciadv.abn4650","type":"journal-article","created":{"date-parts":[[2022,7,29]],"date-time":"2022-07-29T17:58:43Z","timestamp":1659117523000},"source":"Crossref","is-referenced-by-count":24,"title":["Mechanism for selective binding of aromatic compounds on oxygen-rich graphene nanosheets based on molecule size\/polarity matching"],"prefix":"10.1126","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0014-1829","authenticated-orcid":true,"given":"Heyun","family":"Fu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Jiangsu 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5865-4849","authenticated-orcid":true,"given":"Bingyu","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Jiangsu 210023, China."},{"name":"School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Jiangsu 210094, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6190-5522","authenticated-orcid":true,"given":"Dongqiang","family":"Zhu","sequence":"additional","affiliation":[{"name":"Key Laboratory of the Ministry of Education for Earth Surface Processes, School of Urban and Environmental Sciences, Peking University, Beijing 100871, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhicheng","family":"Zhou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Jiangsu 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shidong","family":"Bao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Jiangsu 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9157-4274","authenticated-orcid":true,"given":"Xiaolei","family":"Qu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Jiangsu 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4089-4358","authenticated-orcid":true,"given":"Yong","family":"Guo","sequence":"additional","affiliation":[{"name":"Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes of Ministry of Education, College of Environment, Hohai University, Jiangsu 210098, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7348-4657","authenticated-orcid":true,"given":"Lan","family":"Ling","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shourong","family":"Zheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Jiangsu 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7395-4353","authenticated-orcid":true,"given":"Pu","family":"Duan","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0604-7451","authenticated-orcid":true,"given":"Jingdong","family":"Mao","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, VA 23529, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3188-4828","authenticated-orcid":true,"given":"Klaus","family":"Schmidt-Rohr","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Brandeis University, Waltham, MA 02453, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7374-7063","authenticated-orcid":true,"given":"Shu","family":"Tao","sequence":"additional","affiliation":[{"name":"Key Laboratory of the Ministry of Education for Earth Surface Processes, School of Urban and Environmental Sciences, Peking University, Beijing 100871, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pedro J. 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