{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T23:06:04Z","timestamp":1792796764062,"version":"4.5.0"},"reference-count":77,"publisher":"American Association for the Advancement of Science (AAAS)","issue":"49","content-domain":{"domain":["www.science.org"],"crossmark-restriction":true},"short-container-title":["Sci. Adv."],"published-print":{"date-parts":[[2024,12,6]]},"abstract":"<jats:p>\n            Converting CO\n            <jats:sub>2<\/jats:sub>\n            to methanol is crucial for addressing fuel scarcity and mitigating the greenhouse effect. Cu-based catalysts, with their diverse surface states, offer the potential to control reaction pathways and generate reactive H* species. However, a major challenge lies in oxidizing active Cu\n            <jats:sup>0<\/jats:sup>\n            species by water generated during the catalytic process. While nonreducible metal oxides are beneficial in stabilizing metallic states, their limited capability to generate surface oxygen vacancies (O\n            <jats:sub>V<\/jats:sub>\n            ) hinders CO\n            <jats:sub>2<\/jats:sub>\n            activation. Herein, we present a strategy by doping Nd into a La\n            <jats:sub>2<\/jats:sub>\n            O\n            <jats:sub>2<\/jats:sub>\n            CO\n            <jats:sub>3<\/jats:sub>\n            (LOC) support, enhancing O\n            <jats:sub>V<\/jats:sub>\n            formation by disrupting its lattice dyadicity. This leads to higher Cu\n            <jats:sup>0<\/jats:sup>\n            concentration and improved CO\n            <jats:sub>2<\/jats:sub>\n            activation. The resulting Cu\/LOC:Nd catalyst notably outperforms Cu\/LOC and CuZnAl catalysts, achieving a methanol yield of 9.9 moles of methanol per hour per mole of Cu. Our approach opens up possibilities for enhancing Cu-based catalysts in CO\n            <jats:sub>2<\/jats:sub>\n            conversion.\n          <\/jats:p>","DOI":"10.1126\/sciadv.adr3332","type":"journal-article","created":{"date-parts":[[2024,12,4]],"date-time":"2024-12-04T18:59:12Z","timestamp":1733338752000},"update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":38,"title":["Synthesis of defect-rich La\n            <sub>2<\/sub>\n            O\n            <sub>2<\/sub>\n            CO\n            <sub>3<\/sub>\n            supports for enhanced CO\n            <sub>2<\/sub>\n            -to-methanol conversion efficiency"],"prefix":"10.1126","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4829-9665","authenticated-orcid":true,"given":"Rui","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese 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