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To overcome these issues, we introduce a universal alcohol-based molecule coupling (AMC) method to regulate amorphousness and inhibit V dissolution in VOs (VO\n                    <jats:sub>2<\/jats:sub>\n                    , V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    , and V\n                    <jats:sub>6<\/jats:sub>\n                    O\n                    <jats:sub>13<\/jats:sub>\n                    ), resulting in high-performance cathodes. The strategy enables alcohol molecules with different chain lengths (ethanol, isopropanol, and isobutanol) to couple with VOs by forming V\u2500OH bonds under Lewis acid\u2013based interactions, inducing controlled amorphization. Among these, isopropanol coupling stands out by enabling the formation of short-range ordered amorphous structure (SOA-VO\/Ipr). This structure enhances the reaction kinetics and suppresses V dissolution. As a result, the SOA-VO\/Ipr cathode achieves 219.4 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 100 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , retains 92.6% capacity over 10,000 cycles, and delivers 228.8 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 9.1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    under high loading (21.9 mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) over 3500 cycles, demonstrating a promising method for durable zinc-ion batteries.\n                  <\/jats:p>","DOI":"10.1126\/sciadv.adt7502","type":"journal-article","created":{"date-parts":[[2025,5,23]],"date-time":"2025-05-23T14:00:21Z","timestamp":1748008821000},"update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":53,"title":["Alcohol molecule coupling: A universal approach to modulating amorphousness in vanadium-based cathodes for high-rate and durable aqueous zinc-ion batteries"],"prefix":"10.1126","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3392-2557","authenticated-orcid":true,"given":"Haobin","family":"Song","sequence":"first","affiliation":[{"name":"Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore 487372, Singapore."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4060-7627","authenticated-orcid":true,"given":"Yang-feng","family":"Cui","sequence":"additional","affiliation":[{"name":"Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore 487372, Singapore."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4695-4144","authenticated-orcid":true,"given":"Yifan","family":"Li","sequence":"additional","affiliation":[{"name":"Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore 487372, Singapore."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueliang","family":"Li","sequence":"additional","affiliation":[{"name":"Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore 487372, Singapore."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1690-3541","authenticated-orcid":true,"given":"Yixiang","family":"Li","sequence":"additional","affiliation":[{"name":"Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore 487372, Singapore."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nan","family":"Zhao","sequence":"additional","affiliation":[{"name":"Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore 487372, Singapore."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-2048-4571","authenticated-orcid":true,"given":"Wenjing","family":"Li","sequence":"additional","affiliation":[{"name":"Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore 487372, Singapore."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7252-6106","authenticated-orcid":true,"given":"Chao","family":"Wu","sequence":"additional","affiliation":[{"name":"Institute of Sustainability for Chemical, Energy and Environment (ISCE2), Agency for Science, Technology and Research, 1 Pesek Road Jurong Island, Singapore 627833, Singapore."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8521-3237","authenticated-orcid":true,"given":"Shibo","family":"Xi","sequence":"additional","affiliation":[{"name":"Institute of Sustainability for Chemical, Energy and Environment (ISCE2), Agency for Science, Technology and Research, 1 Pesek Road Jurong Island, Singapore 627833, Singapore."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4188-6421","authenticated-orcid":true,"given":"Shaozhuan","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education &amp; 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