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The key to the success of the asymmetric reaction was the combination of an achiral monophosphine ligand Ph\n            <jats:sub>2<\/jats:sub>\n            P(2-furyl) with a chiral diamine derivative, which enhanced the enantioselectivity and reactivity. Density functional theory calculations revealed the hydrogen bond interactions between the chiral diamine derivative, the achiral monophosphine ligand, and the base anion, which combined to induce the desired enantioselectivity. 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