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This study introduces a \u201ccurvature-programming\u201d strategy to drive electrochemical nitrate reduction by assembling FeCu dual single-atom protrusions on molybdenum carbide quantum dots (FeCu\/MoC\n                    <jats:sub>x<\/jats:sub>\n                    -5 QDs). The high-curvature QDs and protruding geometries mimic active vertex sites, enhancing electric fields to polarize N\u2500O bonds. This delivers nearly 100% NH\n                    <jats:sub>3<\/jats:sub>\n                    Faradaic efficiency over a wide potential window (\u22120.1 to \u22120.4 V versus reversible hydrogen electrode), with an ultralow overpotential (300 mV) and energy consumption (7.52 Wh g\n                    <jats:sub>NH3<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    mg\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). FeCu\/MoC\n                    <jats:sub>x<\/jats:sub>\n                    -5 effectively reduces nitrate levels in wastewater, producing scalable (NH\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    SO\n                    <jats:sub>4<\/jats:sub>\n                    , thus integrating environmental remediation with renewable energy storage. This work provides a promising strategy for developing SACs for broader energy applications.\n                  <\/jats:p>","DOI":"10.1126\/sciadv.aeb8172","type":"journal-article","created":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T09:53:19Z","timestamp":1778579599000},"update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":1,"title":["Curvature-programmed nitrate electroreduction via single-atom protrusions on quantum dots"],"prefix":"10.1126","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2133-4697","authenticated-orcid":true,"given":"Dong","family":"Chen","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong SAR 999077, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaoce","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering, The University of Hong Kong, 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